Progress in the self-assembly of organic/inorganic polyhedral oligomeric silsesquioxane (POSS) hybrids

被引:60
作者
Mohamed, Mohamed Gamal [1 ]
Kuo, Shiao-Wei [1 ]
机构
[1] Natl Sun Yat Sen Univ, Ctr Funct Polymers & Supramol Mat, Dept Mat & Optoelect Sci, Kaohsiung 80424, Taiwan
关键词
HETERONUCLEOBASE-FUNCTIONALIZED BENZOXAZINE; ABA TRIBLOCK COPOLYMERS; BLOCK-COPOLYMER; FRANK-KASPER; SUPRAMOLECULAR STRUCTURES; GIANT SURFACTANTS; SYMMETRY-BREAKING; QUASI-CRYSTAL; SECONDARY STRUCTURES; RAFT POLYMERIZATION;
D O I
10.1039/d2sm00635a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This Review describes recent progress in the self-assembly of organic/inorganic POSS hybrids derived from mono-, di-, and multi-functionalized POSS cages. We highlight the self-assembled structures and physical properties of giant surfactants and chain-end- and side-chain-type hybrids derived from mono-functionalized POSS cages; main-chain-type hybrids derived from di-functionalized POSS cages; and star-shaped hybrids derived from multi-functionalized POSS cages; with various polymeric attachments, including polystyrene, poly(methyl methacrylate), phenolic, PVPh, and polypeptides.
引用
收藏
页码:5535 / 5561
页数:27
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