Two-step nonlinear optical switch in a hydrogen-bonded perovskite-type crystal

被引：13

作者：

Hua, Xiu-Ni ^{[1
]}

Zhang, Wan-Ying ^{[2
]}

Shi, Ping-Ping ^{[1
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China

[2] Bengbu Univ, Sch Sci, Bengbu 233030, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 11期

基金：

中国国家自然科学基金;

关键词：

DESIGN;

D O I：

10.1039/d1cc06306e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Switchable nonlinear optical (NLO) materials have aroused broad interest on account of their captivating optical and electronic properties. We demonstrate a novel perovskite-type crystal with exceptional hydrogen bond interactions that are associated with the onset of reorientational motions of organic cations and thus induce the occurrence of two successive phase transitions to be a two-step NLO switch. This finding affords an alternative approach for the design and assembly of switchable NLO materials.

引用

页码：1712 / 1715

页数：4

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