Cyclopentadienyl mesityl complexes of chromium(II) and chromium(III)

被引:14
作者
Zhou, Wen [1 ]
Therrien, Jeffrey A. [1 ]
Wence, D. Lee K. [1 ]
Yallits, Emily N. [1 ]
Conway, Julia L. [1 ]
Patrick, Brian O. [2 ]
Smith, Kevin M. [1 ]
机构
[1] Univ British Columbia Okanagan, Dept Chem, Kelowna, BC, Canada
[2] Univ British Columbia, Dept Chem, Vancouver, BC, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
CROSS-COUPLING REACTIONS; TRANSITION-METALS; ELECTRONIC-STRUCTURE; ALKYL-HALIDES; PI-COMPLEXES; CHEMISTRY; LIGAND; REACTIVITY; CATALYST; REDUCTION;
D O I
10.1039/c0dt01399d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Chromium(III) mesityl complexes were synthesized by protonolysis of chromocene with 1,3-diisopropylimidazolium chloride or DBU hydrochloride, salt metathesis with Mes-MgBr, and single electron oxidation with iodine.
引用
收藏
页码:337 / 339
页数:3
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