Large scale structures in nanocomposite hydrogels

被引:83
作者
Loizou, E
Butler, P
Porcar, L
Kesselman, E
Talmon, Y
Dundigalla, A
Schmidt, G [1 ]
机构
[1] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA
[2] NIST, Gaithersburg, MD 20899 USA
[3] Technion Israel Inst Technol, IL-32000 Haifa, Israel
关键词
D O I
10.1021/ma047411a
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The physical picture of the large scale structures in nanocomposite hydrogels and some of their unique behavior were discussed. The aqueous solutions of the synthetic hectorite type clay, Laponite RD (LRD) and poly(ethylene oxide) (PEO) were used and the clay particles composed of platelets of high purity and uniform size. It was demonstrated that polymer-clay gels contained structures on a multiple scale length. Analysis suggests that the clay platelets can interconnect by network-active polymer through their edges with many strings being much longer than the 30 nm nominal platelet diameter.
引用
收藏
页码:2047 / 2049
页数:3
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共 19 条
  • [1] Scattering of disklike particle suspensions: Evidence for repulsive interactions and large length scale structure from static light scattering and ultra-small-angle neutron scattering
    Bhatia, S
    Barker, J
    Mourchid, A
    [J]. LANGMUIR, 2003, 19 (03) : 532 - 535
  • [2] Development of a thermal-neutron double-crystal diffractometer for USANS at NIST
    Drews, AR
    Barker, JG
    Glinka, CJ
    Agamalian, M
    [J]. PHYSICA B, 1997, 241 : 189 - 191
  • [3] Unusual multilayered structures in poly(ethylene oxide)/laponite nanocomposite films
    Dundigalla, A
    Lin-Gibson, S
    Ferreiro, V
    Malwitz, MM
    Schmidt, G
    [J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (03) : 143 - 149
  • [4] Swollen liquid-crystalline lamellar phase based on extended solid-like sheets
    Gabriel, JCP
    Camerel, F
    Lemaire, BJ
    Desvaux, H
    Davidson, P
    Batail, P
    [J]. NATURE, 2001, 413 (6855) : 504 - 508
  • [5] The 30 m small-angle neutron scattering instruments at the National Institute of Standards and Technology
    Glinka, CJ
    Barker, JG
    Hammouda, B
    Krueger, S
    Moyer, JJ
    Orts, WJ
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1998, 31 : 430 - 445
  • [6] Structure and formation of a gel of colloidal disks
    Kroon, M
    Vos, WL
    Wegdam, GH
    [J]. PHYSICAL REVIEW E, 1998, 57 (02) : 1962 - 1970
  • [7] Structure and formation of a gel of colloidal disks
    Kroon, M
    Vos, WL
    Wegdam, GH
    [J]. INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1998, 19 (03) : 887 - 894
  • [8] Interaction of polymer with discotic clay particles
    Lal, J
    Auvray, L
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2001, 356 : 503 - 515
  • [9] Interaction of polymer with clays
    Lal, J
    Auvray, L
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2000, 33 (01) : 673 - 676
  • [10] Influence of pyrophosphate or polyethylene oxide on the aggregation and gelation of aqueous laponite dispersions
    Mongondry, P
    Nicolai, T
    Tassin, JF
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 275 (01) : 191 - 196