The coordination chemistry of cyclohexanepolycarboxylate ligands. Structures, conformation and functions

被引：110

作者：

Lin, Zhuojia ^{[1
]}

Tong, Ming-Liang ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Key Lab Bioinorgan & Synthet Chem, Minist Educ,Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2011年 / 255卷 / 3-4期

基金：

中国国家自然科学基金;

关键词：

Cyclohexanepolycarboxylate ligands; Flexible conformation; Coordination polymers; Magnetic materials; Conformational transformation; METAL-ORGANIC FRAMEWORKS; SECONDARY BUILDING UNITS; CRYSTAL-STRUCTURES; CYCLOHEXANEDICARBOXYLATE LIGAND; MACROCYCLIC COMPLEX; PORE-SIZE; ACID; DESIGN; 3D; POLYMERS;

D O I：

10.1016/j.ccr.2010.10.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review gives an overview on the coordination chemistry of eight cyclohexanepolycarboxylic acids, i.e. cyclohexanecarboxylic acid, 1,2-, 1,3- and 1,4-cyclohexanedicarboxylic acid, 1,3,5- and 1,2,4-cyclohexanetricarboxylic acid, 1,2,4,5-cyclohexanetetracarboxylic acid and 1,2,3,4,5,6cyclohexanehexacarboxylic acid, and explores their possible applications in materials science, especially as magnetic materials. The conformational transformation of cyclohexanepolycarboxylic acids in the presence of various metal ions under hydrothermal conditions is included and the a-proton removal mechanism is discussed as well. (C) 2010 Published by Elsevier B.V.

引用

页码：421 / 450

页数：30

共 119 条

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