Structure and Activity of Ni- and Sb-doped SnO2 Ozone Anodes

被引：27

作者：

Christensen, P. A. ^{[1
]}

Zakaria, K. ^{[2
]}

Curtis, T. P. ^{[2
]}

机构：

[1] Newcastle Univ, Sch Chem Engn & Adv Mat, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[2] Newcastle Univ, Sch Civil Engn & Geosci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

OZONE-SCIENCE & ENGINEERING | 2012年 / 34卷 / 01期

关键词：

Ozone; Electrochemical Ozone Generation; Anodes; Electrodes; PERFORATED DIAMOND ELECTRODES; FRACTAL DIMENSION; VOLTAMMETRY; GENERATION; ACID;

D O I：

10.1080/01919512.2012.639687

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Data are presented on the effect of the loading of Ni/Sb-SnO2 on the physical, structural and electrochemical characteristics of this highly active ozone electrocatalyst with the aim of understanding its catalytic activity. The data strongly suggest that, despite the 'cracked earth morphology of the catalysts, the walls of the fissures do not contribute to the observed electroactivity, both in terms of ferrocyanide oxidation or O-3 and O-2 evolution. In addition, the data indicate that there is a surface enrichment of Ni, and hence active sites, with increasing loading.

引用

页码：49 / 56

页数：8

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