Helicity control of a perfluorinated carbon chain within a chiral supramolecular cage monitored by VCD

被引：11
作者：
Bravin, Carlo [1 ]
Mazzeo, Giuseppe [2 ]
Abbate, Sergio [2 ]
Licini, Giulia [1 ]
Longhi, Giovanna [2 ]
Zonta, Cristiano [1 ]
机构：
[1] Univ Padua, Dipartimento Sci Chim, Padua, PD, Italy
[2] Univ Brescia, Dept Mol & Translat Med, Viale Europa 11, I-25123 Brescia, BS, Italy
来源：
CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 13期
关键词：
PERFLUOROALKYL CHAINS; ESI-MS; SPECTROSCOPY; IR; COMPLEXES; ASSEMBLIES; MOLECULES; FIBRILS; SPECTRA; ALKANES;
D O I：
10.1039/d1cc06861j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Confinement within supramolecular systems is the leading technology to finely tune guest functional properties. In this communication we report the synthesis of a chiral supramolecular cage able to bias the helicity of a perfluorinated carbon chain hosted within the cage. We monitor the phenomenon of chiral induction by Vibrational Circular Dichroism (VCD) experiments complemented by DFT calculations over the possible conformers.
引用
收藏
页码：2152 / 2155
页数：4
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