Enzymatic surface hydrolysis of poly(ethylene furanoate) thin films of various crystallinities

被引：96

作者：

Weinberger, S. ^{[1
]}

Haernvall, K. ^{[2
]}

Scaini, D. ^{[3
]}

Ghazaryan, G. ^{[4
]}

Zumstein, M. T. ^{[5
]}

Sander, M. ^{[5
]}

Pellis, A. ^{[1
]}

Guebitz, G. M. ^{[1
,2
]}

机构：

[1] Univ Nat Resources & Life Sci Vienna BOKU, Inst Environm Biotechnol, Konrad Lorenz Str 20, A-3430 Tulln An Der Donau, Austria

[2] Austrian Ctr Ind Biotechnol GmbH ACIB, Konrad Lorenz Str 20, A-3430 Tulln An Der Donau, Austria

[3] Univ Trieste, Dept Life Sci, Piazzale Europa 1, I-34127 Trieste, Italy

[4] ETH, Swiss Fed Inst Technol Zurich, Polymer Technol, Vladimir Prelog Weg 5, CH-8093 Zurich, Switzerland

[5] ETH, Inst Biogeochem & Pollutant Dynam, CH-8092 Zurich, Switzerland

来源：

GREEN CHEMISTRY | 2017年 / 19卷 / 22期

关键词：

THERMOBIFIDA-CELLULOSILYTICA; 2,5-FURANDICARBOXYLIC ACID; ALIPHATIC POLYESTERS; POLY(ETHYLENE-TEREPHTHALATE); POLYMERIZATION; POLYAMIDES;

D O I：

10.1039/c7gc02905e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work reports on the successful production of poly(ethylene furanoate) (PEF) thin films and a comparison of the enzymatic hydrolysis of PEF and poly(ethylene terephthalate) (PET) films with three different crystallinities (0, 10 and 20%). The data suggest that the PEF films are enzymatically hydrolyzed 1.7 times faster than the commonly investigated PET films. QCM-D and SEM/AFM analyses fully confirm the observed reaction trend. The results also show a negative dependence of the hydrolysis rates with the increasing of the film crystallinity.

引用

页码：5381 / 5384

页数：4

共 18 条

[1] Chain Mobility, Thermal, and Mechanical Properties of Poly(ethylene furanoate) Compared to Poly(ethylene terephthalate) [J].

Burgess, Steven K. ;

Leisen, Johannes E. ;

Kraftschik, Brian E. ;

Mubarak, Christopher R. ;

Kriegel, Robert M. ;

Koros, William J. .

MACROMOLECULES, 2014, 47 (04) :1383-1391

[2] Enzymatic Degradation of Aromatic and Aliphatic Polyesters by P. pastoris Expressed Cutinase 1 from Thermobifida cellulosilytica [J].

Gamerith, Caroline ;

Vastano, Marco ;

Ghorbanpour, Sahar M. ;

Zitzenbacher, Sabine ;

Ribitsch, Doris ;

Zumstein, Michael T. ;

Sander, Michael ;

Acero, Enrique Herrero ;

Pellis, Alessandro ;

Guebitz, Georg M. .

FRONTIERS IN MICROBIOLOGY, 2017, 8

[3] Synthesis and Characterization of Novel Renewable Polyesters Based on 2,5-Furandicarboxylic Acid and 2,3-Butanediol [J].

Gubbels, E. ;

Jasinska-Walc, L. ;

Koning, C. E. .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2013, 51 (04) :890-898

[4] Enzymatic synthesis of 2,5-furandicarboxylic acid-based semi-aromatic polyamides: enzymatic polymerization kinetics, effect of diamine chain length and thermal properties [J].

Jiang, Yi ;

Maniar, Dina ;

Woortman, Albert J. J. ;

Loos, Katja .

RSC ADVANCES, 2016, 6 (72) :67941-67953

[5] Enzymatic Polymerization of Furan-2,5-Dicarboxylic Acid-Based Furanic-Aliphatic Polyamides as Sustainable Alternatives to Polyphthalamides [J].

Jiang, Yi ;

Maniar, Dina ;

Woortman, Albert J. J. ;

van Ekenstein, Gert O. R. Alberda ;

Loos, Katja .

BIOMACROMOLECULES, 2015, 16 (11) :3674-3685

[6] A biocatalytic approach towards sustainable furanic-aliphatic polyesters [J].

Jiang, Yi ;

Woortman, Albert J. J. ;

van Ekenstein, Gert O. R. Alberda ;

Loos, Katja .

POLYMER CHEMISTRY, 2015, 6 (29) :5198-5211

[7]

Moffitt R. D., 2016, WO, Patent No. [2016044305 A1, 2016044305]

[8]

Nederberg F., 2014, WO, Patent No. [2013149221 A1, 2013149221]

[9] Enzymatic hydrolysis of poly(ethylene furanoate) [J].

Pellis, Alessandro ;

Haernvall, Karolina ;

Pichler, Christian M. ;

Ghazaryan, Gagik ;

Breinbauer, Rolf ;

Guebitz, Georg M. .

JOURNAL OF BIOTECHNOLOGY, 2016, 235 :47-53

[10] Ultrasound-enhanced enzymatic hydrolysis of poly(ethylene terephthalate) [J].

Pellis, Alessandro ;

Gamerith, Caroline ;

Ghazaryan, Gagik ;

Ortner, Andreas ;

Acero, Enrique Herrero ;

Guebitz, Georg M. .

BIORESOURCE TECHNOLOGY, 2016, 218 :1298-1302

← 1 2 →