Systematic Tuning of the Luminescence Output of Multicomponent Metal-Organic Frameworks

被引:106
作者
Cornelio, Joel [1 ]
Zhou, Tian-You [1 ]
Alkas, Adil [1 ]
Telfer, Shane G. [1 ]
机构
[1] Massey Univ, MacDiarmid Inst Adv Mat & Nanotechnol, Inst Fundamental Sci, Palmerston North, New Zealand
关键词
WHITE-LIGHT EMISSION; COLOR; MOF;
D O I
10.1021/jacs.8b09887
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal-organic frameworks (MOFs) exhibit a broad range of luminescence characteristics due to the vast array of metal ions and organic linkers available as building blocks. Systematic control over the emissive output of MOFs is highly sought after. Methods for tuning emission profiles are emerging based largely on luminescent metal ions and the encapsulation of emissive guests. Herein, we show how the functionalization of the organic linkers of a series of multicomponent MUF-77 (MUF = Massey University Framework) materials can methodically tune their spectral output. This was quantified by chromaticity diagrams. White-light emission was obtained by combining the photophysical characteristics of the three distinct organic fluorophores present in these materials. Our results also show that both (i) energy transfer interactions between the organic components and (ii) noncovalent interactions with guests can also be harnessed to tune the emission. These results establish multicomponent metal-organic frameworks as fluorescent materials with unique spectral characteristics.
引用
收藏
页码:15470 / 15476
页数:7
相关论文
共 44 条
  • [1] Luminescent metal-organic frameworks
    Allendorf, M. D.
    Bauer, C. A.
    Bhakta, R. K.
    Houk, R. J. T.
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) : 1330 - 1352
  • [2] Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations
    An, Jihyun
    Shade, Chad M.
    Chengelis-Czegan, Demetra A.
    Petoud, Stephane
    Rosi, Nathaniel L.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) : 1220 - 1223
  • [3] Luminescent Functional Metal-Organic Frameworks
    Cui, Yuanjing
    Yue, Yanfeng
    Qian, Guodong
    Chen, Banglin
    [J]. CHEMICAL REVIEWS, 2012, 112 (02) : 1126 - 1162
  • [4] A Trichromatic and White-Light-Emitting MOF Composite for Multi-Dimensional and Multi-Response Ratiometric Luminescent Sensing
    Dai, Yue
    Zhang, Jian-Jun
    Liu, Shu-Qin
    Zhou, Huajun
    Sun, Ying-Ji
    Pan, Yu-Zhen
    Ni, Jun
    Yang, Jing-Si
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (38) : 9555 - 9564
  • [5] Dolgopolova EA, 2018, CHEM SOC REV, V47, P4710, DOI [10.1039/c7cs00861a, 10.1039/C7CS00861A]
  • [6] Small-molecule H-bond donors in asymmetric catalysis
    Doyle, Abigail G.
    Jacobsen, Eric N.
    [J]. CHEMICAL REVIEWS, 2007, 107 (12) : 5713 - 5743
  • [7] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage
    Eddaoudi, M
    Kim, J
    Rosi, N
    Vodak, D
    Wachter, J
    O'Keeffe, M
    Yaghi, OM
    [J]. SCIENCE, 2002, 295 (5554) : 469 - 472
  • [8] Mechanistic considerations of guanidine-catalyzed reactions
    Fu, Xiao
    Tan, Choon-Hong
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (29) : 8210 - 8222
  • [9] The Chemistry and Applications of Metal-Organic Frameworks
    Furukawa, Hiroyasu
    Cordova, Kyle E.
    O'Keeffe, Michael
    Yaghi, Omar M.
    [J]. SCIENCE, 2013, 341 (6149) : 974 - +
  • [10] Mixed-Lanthanide Metal Organic Frameworks with Tunable Color and White Light Emission
    Gai, Yanli
    Guo, Qin
    Xiong, Kecai
    Jiang, Feilong
    Li, Chenyuan
    Li, Xin
    Chen, Yan
    Zhu, Chengyuan
    Huang, Qing
    Yao, Rui
    Hong, Maochun
    [J]. CRYSTAL GROWTH & DESIGN, 2017, 17 (03) : 940 - 944