Hybrid Core-Shell Nanoparticles by "Plug and Play" Self-Assembly

被引：12
|
作者：
Pacaud, Benjamin [1 ]
Leclercq, Loic [1 ]
Dechezelles, Jean-Francois [1 ]
Nardello-Rataj, Veronique [1 ]
机构：
[1] Univ Lille, Univ Artois, UCCS, CNRS,Cent Lille,ENSCL,UMR 8181, F-59000 Lille, France
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 67期
关键词：
colloidal tectonics; cyclodextrins; hybrid supramolecular structures; nanoparticles; polyoxometalates; BUILDING-BLOCKS; CYCLODEXTRIN; POLYOXOMETALATE; SYSTEMS; MOLECULES; CHEMISTRY; CLUSTER;
D O I：
10.1002/chem.201804155
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Supramolecular hybrid functional nanoparticles (NPs) can be obtained via the colloidal tectonics approach provided that multiple interactive molecular tectons are used. Herein, the programmable synthesis of novel hybrid core-shell nanoparticles via the following sequential steps is reported: (i) complexation of 1-decanol by the beta-cyclodextrin (beta-CD), (ii) spontaneous self-assembly into CD NPs, (iii) adsorption of polyoxometalate anions, PW12O403-, on the polar neutral interface of the CD NPs. Such an approach paves the way for the design of novel and original materials and systems.
引用
收藏
页码：17672 / 17676
页数：5
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