Fermentation-pervaporation-catalysis integration process for bio-butadiene production using sweet sorghum juice as feedstock

被引：21
作者：
Cai, Di [1 ]
Zhu, Qiangqiang [1 ]
Chen, Changjing [1 ]
Hu, Song [1 ]
Qin, Peiyong [1 ]
Wang, Bin [1 ]
Tan, Tianwei [1 ]
机构：
[1] Beijing Univ Chem Technol, Natl Energy R&D Ctr Biorefinery, 15 Beisanhuan East Rd, Beijing 100029, Peoples R China
来源：
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS | 2018年 / 82卷
基金：
北京市自然科学基金; 中国博士后科学基金;
关键词：
Butadiene; Ethanol fermentation; Pervaporation; Ag/Mg-Si catalyst; FLUORIDE COMPOSITE MEMBRANE; ACETONE-BUTANOL-ETHANOL; MGO-SIO2; CATALYSTS; CONVERSION; RECOVERY; ACID; 1,3-BUTADIENE; BIOREFINERY;
D O I：
10.1016/j.jtice.2017.11.002
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Fermentation-pervaporation-catalysis (FPC) integration process was employed to produce bio-butadiene using sweet sorghum juice as feedstock. After in situ ethanol removal from fermentation broth, permeate of pervaporation membrane (478.6 g/L bio-ethanol) was directly converted into butadiene by an Ag/Mg-Si catalyst. A butadiene yield of 64.1% with a butadiene selectivity of 75.8% was achieved within 6 h of operation. The integration process showed a great potential on high final product yield in a long-term operation. Following this protocol, about 16 g of bio-butadiene was produced from 1 kg sweet sorghum stalk. The integration process showed a potential in further application for bio-butadiene and materials production. (C) 2017 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：137 / 143
页数：7
相关论文
共 28 条
[1]   Ex Situ and Operando Studies on the Role of Copper in Cu-Promoted SiO2-MgO Catalysts for the Lebedev Ethanol-to-Butadiene Process [J].
Angelici, Carlo ;
Meirer, Florian ;
van der Eerden, Ad M. J. ;
Schaink, Herrick L. ;
Goryachev, Andrey ;
Hofmann, Jan P. ;
Hensen, Emiel J. M. ;
Weckhuysen, Bert M. ;
Bruijnincx, Pieter C. A. .
ACS CATALYSIS, 2015, 5 (10) :6005-6015
[2]   Influence of acid-base properties on the Lebedev ethanol-to-butadiene process catalyzed by SiO2-MgO materials [J].
Angelici, Carlo ;
Velthoen, Marjolein E. Z. ;
Weckhuysen, Bert M. ;
Bruijnincx, Pieter C. A. .
CATALYSIS SCIENCE & TECHNOLOGY, 2015, 5 (05) :2869-2879
[3]   Effect of Preparation Method and CuO Promotion in the Conversion of Ethanol into 1,3-Butadiene over SiO2-MgO Catalysts [J].
Angelici, Carlo ;
Velthoen, Marjolein E. Z. ;
Weckhuysen, Bert M. ;
Bruijnincx, Pieter C. A. .
CHEMSUSCHEM, 2014, 7 (09) :2505-2515
[4]   Selective production of 1,3-butadiene using glucose fermentation liquor [J].
Baek, Jayeon ;
Kim, Tae Yong ;
Kim, Wooyoung ;
Lee, Hee Jong ;
Yi, Jongheop .
GREEN CHEMISTRY, 2014, 16 (07) :3501-3507
[5]   Challenges and opportunities in improving the production of bio-ethanol [J].
Baeyens, Jan ;
Kang, Qian ;
Appels, Lise ;
Dewil, Raf ;
Lv, Yongqin ;
Tan, Tianwei .
PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2015, 47 :60-88
[6]   Shale Gas Revolution: An Opportunity for the Production of Biobased Chemicals? [J].
Bruijnincx, Pieter C. A. ;
Weckhuysen, Bert M. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (46) :11980-11987
[7]   Immobilized ethanol fermentation coupled to pervaporation with silicalite-1/polydimethylsiloxane/polyvinylidene fluoride composite membrane [J].
Cai, Di ;
Hu, Song ;
Chen, Changjing ;
Wang, Yong ;
Zhang, Changwei ;
Miao, Qi ;
Qin, Peiyong ;
Tan, Tianwei .
BIORESOURCE TECHNOLOGY, 2016, 220 :124-131
[8]   Acetone-butanol-ethanol from sweet sorghum juice by an immobilized fermentation-gas stripping integration process [J].
Cai, Di ;
Wang, Yong ;
Chen, Changjing ;
Qin, Peiyong ;
Miao, Qi ;
Zhang, Changwei ;
Li, Ping ;
Tan, Tianwei .
BIORESOURCE TECHNOLOGY, 2016, 211 :704-710
[9]   Gas stripping-pervaporation hybrid process for energy-saving product recovery from acetone-butanol-ethanol (ABE) fermentation broth [J].
Cai, Di ;
Chen, Huidong ;
Chen, Changjing ;
Hu, Song ;
Wang, Yong ;
Chang, Zhen ;
Miao, Qi ;
Qin, Peiyong ;
Wang, Zheng ;
Wang, Jianhong ;
Tan, Tianwei .
CHEMICAL ENGINEERING JOURNAL, 2016, 287 :1-10
[10]   Fundamental Issues of Catalytic Conversion of Bio-Ethanol into Butadiene [J].
Ezinkwo, Godwin O. ;
Tretyakov, Valentine Philippovich ;
Aliyu, Auwal ;
Ilolov, Akhmadsho Mamadshoevich .
CHEMBIOENG REVIEWS, 2014, 1 (05) :194-203
123