Controlled Synthesis of (Co)polymers of NH-Unsubstituted 5-Vinyltetrazole and N-Vinyl Succinimide

被引：1
作者：
Sivtsov, E. V. [1 ,2 ]
Krygina, D. M. [1 ]
Gostev, A. I. [2 ]
机构：
[1] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
[2] St Petersburg State Inst Technol Tech Univ, St Petersburg 190013, Russia
来源：
RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2022年 / 95卷 / 06期
关键词：
5-vinyltetrazole; RAFT polymerization; reversible chain transfer; polymerization kinetics; polymer microstructure; FRAGMENTATION CHAIN-TRANSFER; CONTROLLED RADICAL POLYMERIZATION; RAFT POLYMERIZATION; TRITHIOCARBONATES; COPOLYMERS; STYRENE;
D O I：
10.1134/S1070427222060064
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Controlled radical polymerization with reversible chain transfer by addition-fragmentation mechanism of NH-unsubstituted 5-vinyltetrazole and its copolymerization with N-vinyl succinimide in the presence of dibenzyltrithiocarbonate was conducted. The polymerization kinetics and molecular weight parameters of the synthesized polymers were studied using NMR spectroscopy and gel permeation chromatography. The chain transfer constants of dibenzyl trithiocarbonate for the homopolymerization of 5-vinyltetrazole and its copolymerization with N-vinyl succinimide were evaluated for different compositions of the monomer mixture. The copolymerization constants of the monomers were determined and the microstructure of the resulting copolymers was described.
引用
收藏
页码：812 / 827
页数：16
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  • [1] RAFT Polymerization of Bio-Based 1-Vinyl-4-dianhydrohexitol-1,2,3-triazole Stereoisomers Obtained via Click Chemistry
    Beghdadi, Samir
    Miladi, Imen Abdelhedi
    Ben Romdhane, Hatem
    Bernard, Julien
    Drockenmuller, Eric
    [J]. BIOMACROMOLECULES, 2012, 13 (12) : 4138 - 4145
  • [2] Radical Substitution of the Dithiocarbonyl Group of Poly(methyl methacrylate) Obtained by Reversible Addition-Fragmentation Chain Transfer Polymerization
    Bekanova, M. Z.
    Neumolotov, N. K.
    Jablanovic, A. D.
    Plutalova, A. V.
    Chernikova, E. V.
    [J]. POLYMER SCIENCE SERIES C, 2019, 61 (01) : 186 - 197
  • [3] Thermal stability of RAFT-based poly(methyl methacrylate): A kinetic study of the dithiobenzoate and trithiocarbonate end-group effect
    Bekanova, Marianna Z.
    Neumolotov, Nikolay K.
    Jablanovic, Anastasija D.
    Plutalova, Anna V.
    Chernikova, Elena V.
    Kudryavtsev, Yaroslav V.
    [J]. POLYMER DEGRADATION AND STABILITY, 2019, 164 : 18 - 27
  • [4] Controlled radical polymerization of styrene mediated by dithiobenzoates as reversible addition-fragmentation chain-transfer agents
    Chernikova, E. V.
    Tarasenko, A. V.
    Garina, E. S.
    Golubev, V. B.
    [J]. POLYMER SCIENCE SERIES A, 2006, 48 (10) : 1046 - 1057
  • [5] Controlled radical polymerization of styrene and n-butyl acrylate mediated by trithiocarbonates
    Chernikova, E. V.
    Terpugova, P. S.
    Garina, E. S.
    Golubev, V. B.
    [J]. POLYMER SCIENCE SERIES A, 2007, 49 (02) : 108 - 119
  • [6] Reversible Addition-Fragmentation Chain-Transfer Polymerization: Fundamentals and Use in Practice
    Chernikova, E. V.
    Sivtsov, E. V.
    [J]. POLYMER SCIENCE SERIES B, 2017, 59 (02) : 117 - 146
  • [7] Controlled synthesis of copolymers of vinyl acetate and n-butyl acrylate mediated by trithiocarbonates as reversible addition-fragmentation chain-transfer agents
    Chernikova, E. V.
    Yulusov, V. V.
    Mineeva, K. O.
    Garina, E. S.
    Sivtsov, E. V.
    [J]. POLYMER SCIENCE SERIES B, 2012, 54 (7-8) : 349 - 360
  • [8] Controlled radical polymerization of acrylonitrile in the presence of trithiocarbonates as reversible addition-fragmentation chain transfer agents
    Chernikova, E. V.
    Poteryaeva, Z. A.
    Belyaev, S. S.
    Sivtsov, E. V.
    [J]. RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2011, 84 (06) : 1031 - 1039
  • [9] Pseudoliving radical polymerization of methyl methacrylate in the presence of S,S'-bis(methyl-2-isobutyrate) trithiocarbonate
    Chernikova, E. V.
    Terpugova, P. S.
    Baskakov, A. A.
    Plutalova, A. V.
    Garina, E. S.
    Sivtsov, E. V.
    [J]. POLYMER SCIENCE SERIES B, 2010, 52 (3-4) : 119 - 128
  • [10] Controlled synthesis of acrylic homo- and copolymers in the presence of trithiocarbonates as reversible addition-fragmentation chain transfer agents
    Chernikova, E. V.
    Terpugova, P. S.
    Trifilov, M. Yu.
    Garina, E. S.
    Golubev, V. B.
    Sivtsov, E. V.
    [J]. POLYMER SCIENCE SERIES A, 2009, 51 (06) : 658 - 666
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