CO hydrocarbon formation mechanism and kinetics in the reaction of heterogeneous-catalytic carbon dioxide hydrogenation over transition metals

被引：0

作者：

Tripolsky, AI ^{[1
]}

Odnovolik, VI ^{[1
]}

Pavlenko, NV ^{[1
]}

机构：

[1] NATL ACAD SCI UKRAINE,LV PISARZHEVSKY PHYS CHEM INST,UA-252039 KIEV,UKRAINE

来源：

TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1996年 / 32卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A mechanism for the CO-formation of carbon monoxide, methane and higher (C-2+) hydrocarbons from carbon dioxide in the presence of some transitional metals was grounded A complete kinetic model for the process was derived, which quantitatively characterizes the body of experimental data.

引用

页码：107 / 112

页数：6

共 11 条

[1] KAIM V, 1987, KATALIZ C1 KHIMII, P295
[2] KHIMMELBLAU D, 1975, PRIKLADNOE NELINEINO, P534
[3] ODNOVOLIK VI, 1995, UKR KHIM ZH, V61, P42
[4] PAVLENKO NV, 1989, USP KHIM+, V58, P767
[5] Popova N.M., 1979, ADSORBTSIYA VZAIMODE, P278
[6] ANALYSIS OF THE IR-SPECTRAL BEHAVIOR OF ADSORBED CO FORMED IN H2+CO2 SURFACE INTERACTION OVER SUPPORTED RHODIUM
SOLYMOSI, F
PASZTOR, M
[J]. JOURNAL OF CATALYSIS, 1987, 104 (02) : 312 - 322
[7] TRETYAKOV II, 1964, MEKHANISM VZAIMODEIS, P106
[8] TRIPLSKII AI, 1995, UKR KHIM ZH, V61, P22
[9] Tripol'skii A. I., 1995, UKR KHIM ZH, V61, P31
[10] TRIPOLSKII AI, 1994, UKR KHIM ZH, V60, P827

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