The potential controlled Fenton reaction at liquid|liquid interfaces as the source of hydroxyl radicals

被引：8
作者：
Brusová, Z
Stulík, K
Marecek, K
机构：
[1] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, CR-18223 Prague 8, Czech Republic
[2] Charles Univ Prague, Fac Sci, Dept Analyt Chem, Prague 12840 2, Czech Republic
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2004年 / 563卷 / 02期
关键词：
liquid|liquid interfaces; homogeneous reaction; OH-; radicals; Fenton reaction;
D O I：
10.1016/j.jelechem.2003.09.021
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The Fenton reaction was studied voltammetrically at a water\1,2-dichloroethane interface, with hydrogen peroxide in the aqueous phase and (ferrocenylmethyl)trimethylammonium cation (TMFc(+)) in the organic phase. The reaction mechanism was verified and the reaction kinetics established. It has been shown, that this system can be used for controlled production of OH-radicals that can possibly be applied to initiating polymerization of suitable monomers adsorbed at the interface. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：277 / 281
页数：5
相关论文
共 15 条
[1]   THE KINETICS OF POLYMERISATION REACTIONS IN AQUEOUS SOLUTION [J].
BAXENDALE, JH ;
EVANS, MG ;
KILHAM, JK .
TRANSACTIONS OF THE FARADAY SOCIETY, 1946, 42 (11) :668-675
[2]   THE MECHANISM AND KINETICS OF THE INITIATION OF POLYMERISATION BY SYSTEMS CONTAINING HYDROGEN PEROXIDE [J].
BAXENDALE, JH ;
EVANS, MG ;
PARK, GS .
TRANSACTIONS OF THE FARADAY SOCIETY, 1946, 42 (3-4) :155-169
[3]   Formation of oligomers of methyl- and phenyl-pyrrole at an electrified liquid/liquid interface [J].
Cunnane, VJ ;
Evans, U .
CHEMICAL COMMUNICATIONS, 1998, (19) :2163-2164
[4]  
Fenton H. J. H., 1894, J CHEM SOC, V65, P899, DOI DOI 10.1039/CT8946500899
[5]   Phospholipid monolayers studied by a combination of cyclic voltammetry and Langmuir techniques at the water | 1,2-dichloroethane interface [J].
Grandell, D ;
Murtomäki, L ;
Kontturi, K ;
Sundholm, G .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 463 (02) :242-247
[6]   On the catalysis of hydroperoxide. [J].
Haber, F ;
Weiss, J .
NATURWISSENSCHAFTEN, 1932, 20 :948-950
[7]  
Koryta J., 1983, ION SELECTIVE ELECTR
[8]   Formation of a polymer layer from monomers adsorbed at a liquid | liquid interface [J].
Maeda, K ;
Jänchenová, H ;
Lhotsky, A ;
Stibor, I ;
Budka, J ;
Marecek, V .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 516 (1-2) :103-109
[9]  
MAEDA K, 2001, ANAL SCI, V17, pI325
[10]   CHARGE-TRANSFER ACROSS A POLYMER GEL LIQUID INTERFACE - DETERMINATION OF IONOPHORES [J].
MARECEK, V ;
JANCHENOVA, H ;
BREZINA, M ;
BETTI, M .
ANALYTICA CHIMICA ACTA, 1991, 244 (01) :15-19
12