Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene

被引：75

作者：

De Baerdemaeker, Trees ^{[1
]}

Feyen, Mathias ^{[2
]}

Mueller, Ulrich ^{[2
]}

Yilmaz, Bilge ^{[3
]}

Xiao, Feng-Shou ^{[4
]}

Zhang, Weiping ^{[5
]}

Yokoi, Toshiyuki ^{[6
]}

Bao, Xinhe ^{[7
]}

Gies, Hermann ^{[8
]}

De Vos, Dirk E. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Leuven, Belgium

[2] BASF SE, Proc Res & Chem Engn, D-67056 Ludwigshafen, Germany

[3] BASF Corp, Proc Catalysts & Technol, Iselin, NJ 08830 USA

[4] Zhejiang Univ, Hangzhou 310028, Zhejiang, Peoples R China

[5] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China

[6] Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 2268503, Japan

[7] Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[8] Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany

来源：

ACS CATALYSIS | 2015年 / 5卷 / 06期

关键词：

1,3-butadiene; ethanol; zinc silicate; hemimorphite; heterogeneous catalysis; silica impregnation; MAGNESIUM-OXIDE; METAL-OXIDES; BUTADIENE; HYDROXYAPATITE; TRANSFORMATION; SELECTIVITY; BASICITY; ACETONE; LEBEDEV;

D O I：

10.1021/acscatal.5b00376

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Silica-supported catalysts for the conversion of ethanol to 1,3-butadiene were investigated. The combination of Hf(IV) and Zn(II) resulted in a stable, active, and selective catalyst in which the Zn(II) effectively suppressed the dehydration activity of Hf(IV); the catalyst preparation method plays a crucial role. Using the crystalline Zn-silicate hemimorphite as an alternative Zn(II) source proved to be even more successful in suppressing ethanol dehydration.

引用

页码：3393 / 3397

页数：5

共 50 条

[41] Development of Hf-containing SBA-15 catalysts with highly dispersed active sites for 1,3-butadiene production from ethanol and acetaldehyde [J].

Osuga, Ryota ;

Fang, Peixuan ;

Nishiyama, Haruka ;

Takizawa, Koji ;

Yagihashi, Noritoshi ;

Yokoi, Toshiyuki ;

Kondo, Junko N. .

MICROPOROUS AND MESOPOROUS MATERIALS, 2022, 346

[42] From Sugars to Wheels: The Conversion of Ethanol to 1,3-Butadiene over Metal-Promoted Magnesia-Silicate Catalysts [J].

Shylesh, Sankaranarayanapillai ;

Gokhale, Amit A. ;

Scown, Corinne D. ;

Kim, Daeyoup ;

Ho, Christopher R. ;

Bell, Alexis T. .

CHEMSUSCHEM, 2016, 9 (12) :1462-1472

[43] ZnTa-TUD-1 as an easily prepared, highly efficient catalyst for the selective conversion of ethanol to 1,3-butadiene [J].

Pomalaza, G. ;

Vofo, G. ;

Capron, M. ;

Dumeignil, F. .

GREEN CHEMISTRY, 2018, 20 (14) :3203-3209

[44] A DFT study on Zr-SBA-15 catalyzed conversion of ethanol to 1,3-butadiene [J].

Dong, Xiuqin ;

Lu, Jia ;

Yu, Yingzhe ;

Zhang, Minhua .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20 (18) :12970-12978

[45] Ethanol Conversion to 1,3-Butadiene on ZnO/MgO-SiO2 Catalysts: Effect of ZnO Content and MgO:SiO2 Ratio [J].

Larina, Olga V. ;

Kyriienko, Pavlo I. ;

Soloviev, Sergiy O. .

CATALYSIS LETTERS, 2015, 145 (05) :1162-1168

[46] 1,3-Butadiene production from ethanol-water mixtures over Zn-La-Zr-Si oxide catalyst [J].

Larina, Olga V. ;

Remezovskyi, Ivan M. ;

Kyriienko, Pavlo I. ;

Soloviev, Sergiy O. ;

Orlyk, Svitlana M. .

REACTION KINETICS MECHANISMS AND CATALYSIS, 2019, 127 (02) :903-915

[47] Novel Methylaluminoxane-Activated Neodymium Isopropoxide Catalysts for 1,3-Butadiene Polymerization and 1,3-Butadiene/Isoprene Copolymerization [J].

Hu, Yanming ;

Dong, Weimin ;

Masuda, Toshio .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2013, 214 (19) :2172-2180

[48] Recent Advances in Metal-Zeolite Catalysts for Ethanol to 1,3-Butadiene Conversion: Active Metal Sites, Mechanisms, and Future Challenges [J].

Li, Xianquan ;

Zhao, Yujia ;

Pang, Jifeng ;

Gao, Pan ;

Zheng, Mingyuan ;

Hou, Guangjin .

ACS CATALYSIS, 2025, 15 (06) :5053-5085

[49] Catalytic conversion of ethanol to 1,3-butadiene on MgO: A comprehensive mechanism elucidation using DFT calculations [J].

Taifan, William E. ;

Bucko, Tomas ;

Baltrusaitis, Jonas .

JOURNAL OF CATALYSIS, 2017, 346 :78-91

[50] Heteroatom zeolites with a high content of framework metal sites as Lewis-acid catalysts for the conversion of ethanol-acetaldehyde to 1,3-butadiene [J].

Jiang, Haoxi ;

Yi, Liping ;

Yang, Guochao ;

Wang, Lingtao .

CATALYSIS SCIENCE & TECHNOLOGY, 2023, 13 (01) :245-256

← 1 2 3 4 5 →