Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene

被引：72

作者：

De Baerdemaeker, Trees ^{[1
]}

Feyen, Mathias ^{[2
]}

Mueller, Ulrich ^{[2
]}

Yilmaz, Bilge ^{[3
]}

Xiao, Feng-Shou ^{[4
]}

Zhang, Weiping ^{[5
]}

Yokoi, Toshiyuki ^{[6
]}

Bao, Xinhe ^{[7
]}

Gies, Hermann ^{[8
]}

De Vos, Dirk E. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Leuven, Belgium

[2] BASF SE, Proc Res & Chem Engn, D-67056 Ludwigshafen, Germany

[3] BASF Corp, Proc Catalysts & Technol, Iselin, NJ 08830 USA

[4] Zhejiang Univ, Hangzhou 310028, Zhejiang, Peoples R China

[5] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China

[6] Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 2268503, Japan

[7] Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[8] Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany

来源：

ACS CATALYSIS | 2015年 / 5卷 / 06期

关键词：

1,3-butadiene; ethanol; zinc silicate; hemimorphite; heterogeneous catalysis; silica impregnation; MAGNESIUM-OXIDE; METAL-OXIDES; BUTADIENE; HYDROXYAPATITE; TRANSFORMATION; SELECTIVITY; BASICITY; ACETONE; LEBEDEV;

D O I：

10.1021/acscatal.5b00376

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Silica-supported catalysts for the conversion of ethanol to 1,3-butadiene were investigated. The combination of Hf(IV) and Zn(II) resulted in a stable, active, and selective catalyst in which the Zn(II) effectively suppressed the dehydration activity of Hf(IV); the catalyst preparation method plays a crucial role. Using the crystalline Zn-silicate hemimorphite as an alternative Zn(II) source proved to be even more successful in suppressing ethanol dehydration.

引用

页码：3393 / 3397

页数：5

共 32 条

[1] Chemocatalytic Conversion of Ethanol into Butadiene and Other Bulk Chemicals
Angelici, Carlo
Weckhuysen, Bert M.
Bruijnincx, Pieter C. A.
[J]. CHEMSUSCHEM, 2013, 6 (09) : 1595 - 1614
[2] Breuer K, 1999, ANGEW CHEM INT EDIT, V38, P1401, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1401::AID-ANIE1401>3.0.CO
[3] 2-4
[4] Butadiene production from bioethanol and acetaldehyde over tantalum oxide-supported ordered mesoporous silica catalysts
Chae, Ho-Jeong
Kim, Tae-Wan
Moon, Young-Kyun
Kim, Han-Kyu
Jeong, Kwang-Eun
Kim, Chul-Ung
Jeong, Soon-Yong
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 150 : 596 - 604
[5] On the Chemistry of Ethanol on Basic Oxides: Revising Mechanisms and Intermediates in the Lebedev and Guerbet reactions
Chieregato, Alessandro
Ochoa, Juliana Velasquez
Bandinelli, Claudia
Fornasari, Giuseppe
Cavani, Fabrizio
Mella, Massimo
[J]. CHEMSUSCHEM, 2015, 8 (02) : 377 - 388
[6] Role of oxygen vacancies in the basicity of ZnO: From the model methylbutynol conversion to the ethanol transformation application
Drouilly, Charlotte
Krafft, Jean-Marc
Averseng, Frederic
Lauron-Pernot, Helene
Bazer-Bachi, Delphine
Chizallet, Celine
Lecocq, Vincent
Costentin, Guylene
[J]. APPLIED CATALYSIS A-GENERAL, 2013, 453 : 121 - 129
[7] Creation of a continuous process for bio-ethanol to butadiene conversion via the use of a process initiator
Ezinkwo, G. O.
Tretjakov, V. F.
Talyshinky, R. M.
Ilolov, A. M.
Mutombo, T. A.
[J]. CATALYSIS COMMUNICATIONS, 2014, 43 : 207 - 212
[8] STUDY OF THE MEERWEIN-PONDORFF-VERLEY REACTION BETWEEN ETHANOL AND ACETONE ON VARIOUS METAL-OXIDES
IVANOV, VA
BACHELIER, J
AUDRY, F
LAVALLEY, JC
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1994, 91 (01): : 45 - 59
[9] Ternary Ag/MgO-SiO2 Catalysts for the Conversion of Ethanol into Butadiene
Janssens, Wout
Makshina, Ekaterina V.
Vanelderen, Pieter
De Clippel, Filip
Houthoofd, Kristof
Kerkhofs, Stef
Martens, Johan A.
Jacobs, Pierre A.
Sels, Bert F.
[J]. CHEMSUSCHEM, 2015, 8 (06) : 994 - 1008
[10] Investigations into the conversion of ethanol into 1,3-butadiene
Jones, Matthew D.
Keir, Callum G.
Di Iulio, Carlo
Robertson, Ruth A. M.
Williams, Cliff V.
Apperley, David C.
[J]. CATALYSIS SCIENCE & TECHNOLOGY, 2011, 1 (02) : 267 - 272

← 1 2 3 4 →