Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene

被引：76
作者：
De Baerdemaeker, Trees [1 ]
Feyen, Mathias [2 ]
Mueller, Ulrich [2 ]
Yilmaz, Bilge [3 ]
Xiao, Feng-Shou [4 ]
Zhang, Weiping [5 ]
Yokoi, Toshiyuki [6 ]
Bao, Xinhe [7 ]
Gies, Hermann [8 ]
De Vos, Dirk E. [1 ]
机构：
[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Leuven, Belgium
[2] BASF SE, Proc Res & Chem Engn, D-67056 Ludwigshafen, Germany
[3] BASF Corp, Proc Catalysts & Technol, Iselin, NJ 08830 USA
[4] Zhejiang Univ, Hangzhou 310028, Zhejiang, Peoples R China
[5] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
[6] Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 2268503, Japan
[7] Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
[8] Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany
来源：
ACS CATALYSIS | 2015年 / 5卷 / 06期
关键词：
1,3-butadiene; ethanol; zinc silicate; hemimorphite; heterogeneous catalysis; silica impregnation; MAGNESIUM-OXIDE; METAL-OXIDES; BUTADIENE; HYDROXYAPATITE; TRANSFORMATION; SELECTIVITY; BASICITY; ACETONE; LEBEDEV;
D O I：
10.1021/acscatal.5b00376
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Silica-supported catalysts for the conversion of ethanol to 1,3-butadiene were investigated. The combination of Hf(IV) and Zn(II) resulted in a stable, active, and selective catalyst in which the Zn(II) effectively suppressed the dehydration activity of Hf(IV); the catalyst preparation method plays a crucial role. Using the crystalline Zn-silicate hemimorphite as an alternative Zn(II) source proved to be even more successful in suppressing ethanol dehydration.
引用
收藏
页码：3393 / 3397
页数：5
相关论文
共 32 条
[1]   Chemocatalytic Conversion of Ethanol into Butadiene and Other Bulk Chemicals [J].
Angelici, Carlo ;
Weckhuysen, Bert M. ;
Bruijnincx, Pieter C. A. .
CHEMSUSCHEM, 2013, 6 (09) :1595-1614
[2]  
Breuer K, 1999, ANGEW CHEM INT EDIT, V38, P1401, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1401::AID-ANIE1401>3.0.CO
[3]  
2-4
[4]   Butadiene production from bioethanol and acetaldehyde over tantalum oxide-supported ordered mesoporous silica catalysts [J].
Chae, Ho-Jeong ;
Kim, Tae-Wan ;
Moon, Young-Kyun ;
Kim, Han-Kyu ;
Jeong, Kwang-Eun ;
Kim, Chul-Ung ;
Jeong, Soon-Yong .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 150 :596-604
[5]   On the Chemistry of Ethanol on Basic Oxides: Revising Mechanisms and Intermediates in the Lebedev and Guerbet reactions [J].
Chieregato, Alessandro ;
Ochoa, Juliana Velasquez ;
Bandinelli, Claudia ;
Fornasari, Giuseppe ;
Cavani, Fabrizio ;
Mella, Massimo .
CHEMSUSCHEM, 2015, 8 (02) :377-388
[6]   Role of oxygen vacancies in the basicity of ZnO: From the model methylbutynol conversion to the ethanol transformation application [J].
Drouilly, Charlotte ;
Krafft, Jean-Marc ;
Averseng, Frederic ;
Lauron-Pernot, Helene ;
Bazer-Bachi, Delphine ;
Chizallet, Celine ;
Lecocq, Vincent ;
Costentin, Guylene .
APPLIED CATALYSIS A-GENERAL, 2013, 453 :121-129
[7]   Creation of a continuous process for bio-ethanol to butadiene conversion via the use of a process initiator [J].
Ezinkwo, G. O. ;
Tretjakov, V. F. ;
Talyshinky, R. M. ;
Ilolov, A. M. ;
Mutombo, T. A. .
CATALYSIS COMMUNICATIONS, 2014, 43 :207-212
[8]   STUDY OF THE MEERWEIN-PONDORFF-VERLEY REACTION BETWEEN ETHANOL AND ACETONE ON VARIOUS METAL-OXIDES [J].
IVANOV, VA ;
BACHELIER, J ;
AUDRY, F ;
LAVALLEY, JC .
JOURNAL OF MOLECULAR CATALYSIS, 1994, 91 (01) :45-59
[9]   Ternary Ag/MgO-SiO2 Catalysts for the Conversion of Ethanol into Butadiene [J].
Janssens, Wout ;
Makshina, Ekaterina V. ;
Vanelderen, Pieter ;
De Clippel, Filip ;
Houthoofd, Kristof ;
Kerkhofs, Stef ;
Martens, Johan A. ;
Jacobs, Pierre A. ;
Sels, Bert F. .
CHEMSUSCHEM, 2015, 8 (06) :994-1008
[10]   Investigations into the conversion of ethanol into 1,3-butadiene [J].
Jones, Matthew D. ;
Keir, Callum G. ;
Di Iulio, Carlo ;
Robertson, Ruth A. M. ;
Williams, Cliff V. ;
Apperley, David C. .
CATALYSIS SCIENCE & TECHNOLOGY, 2011, 1 (02) :267-272
1234