Polymerization of methyl methacrylate in the presence of o-iminoquinones: Reversible and irreversible inhibition

被引：5
作者：
Vaganova, L. B. [1 ]
Lizyakina, O. S. [1 ]
Chegerev, M. G. [2 ]
Piskunov, A. V. [2 ]
Grishin, D. F. [1 ]
机构：
[1] Lobachevsky State Univ Nizhny Novgorod, Nizhnii Novgorod 603950, Russia
[2] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia
来源：
POLYMER SCIENCE SERIES B | 2017年 / 59卷 / 05期
基金：
俄罗斯基础研究基金会;
关键词：
TRANSFER RADICAL POLYMERIZATION; IMINOSEMIQUINONE COMPLEX; METAL-COMPLEXES; TIN(IV); QUINONES; STYRENE;
D O I：
10.1134/S1560090417050165
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
New regulators of radical polymerization of methyl methacrylate based on N-(aryl)-o-iminoquinones of various structures are proposed. It is shown that samples of polymethylmethacrylate with the participation of N-(aryl)-o-iminobenzoquinones could be used as macroinitiators of polymerization. Optimal conditions to synthesize polymers in the presence of o-iminobenzoquinones are determined, which make it possible to obtain polymethylmethacrylate with a polydispersity coefficient of no more than 1.5 on deep conversions during bulk polymerization.
引用
收藏
页码：506 / 515
页数：10
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