Controlled chemical modifications of chitosan.: Characterization and investigation of original properties

被引:22
作者
Auzély, R [1 ]
Rinaudo, M [1 ]
机构
[1] Univ Grenoble 1, CNRS, CERMAV, Lab Associe, F-38041 Grenoble 9, France
关键词
chitosan; chitosan-adamantane; chitosan-cyclodextrin; chitosan-surfactant interaction; gels; host-guest systems;
D O I
10.1002/mabi.200300018
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The main techniques developed to characterize chitosan are recalled. The interaction of chitosan with oppositely charged surfactants was investigated giving very important surface activity effects, A few chemical modifications are described and the new properties obtained are mentioned: alkylation gives amphiphilic polymers having interesting thickening behavior; grafting cyclodextrin (chit-CD) gives a polymer able to include hydrophobic molecules; grafting adamantane gives an amphiphilic polymer able to specifically interact with chit-CD forming a temporary network with gel-like behavior.
引用
收藏
页码:562 / 565
页数:4
相关论文
共 14 条
[1]   New supramolecular assemblies of a cyclodextrin-grafted chitosan through specific complexation [J].
Auzély-Velty, R ;
Rinaudo, M .
MACROMOLECULES, 2002, 35 (21) :7955-7962
[2]   Chitosan derivatives bearing pendant cyclodextrin cavities:: Synthesis and inclusion performance [J].
Auzély-Velty, R ;
Rinaudo, M .
MACROMOLECULES, 2001, 34 (11) :3574-3580
[3]   Interfacial properties of dynamic association between chitin derivatives and surfactants [J].
Babak, V ;
Lukina, I ;
Vikhoreva, G ;
Desbrières, J ;
Rinaudo, M .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1999, 147 (1-2) :139-148
[4]  
BABAK V, COMMUNICATION
[5]   Formation of an ordered nanostructure in surfactant-polyelectrolyte complexes formed by interfacial diffusion [J].
Babak, VG ;
Merkovich, EA ;
Desbrières, J ;
Rinaudo, M .
POLYMER BULLETIN, 2000, 45 (01) :77-81
[6]   Characterization of chitosan by steric exclusion chromatography [J].
Brugnerotto, J ;
Desbrières, J ;
Roberts, G ;
Rinaudo, M .
POLYMER, 2001, 42 (25) :9921-9927
[7]   Structural and dynamical properties of semirigid polyelectrolyte solutions: A light-scattering study [J].
Buhler, E ;
Rinaudo, M .
MACROMOLECULES, 2000, 33 (06) :2098-2106
[8]   Reversible thermothickening of aqueous solutions of polycations from natural origin [J].
Desbrieres, J ;
Rinaudo, M ;
Chtcheglova, L .
MACROMOLECULAR SYMPOSIA, 1997, 113 :135-149
[9]   Hydrophobic derivatives of chitosan: Characterization and rheological behaviour [J].
Desbrieres, J ;
Martinez, C ;
Rinaudo, M .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 1996, 19 (01) :21-28
[10]   Predicted influence of N-acetyl group content on the conformational extension of chitin and chitosan chains [J].
Mazeau, K ;
Pérez, S ;
Rinaudo, M .
JOURNAL OF CARBOHYDRATE CHEMISTRY, 2000, 19 (09) :1269-1284