Water-promoted ammonia oxidation by a platinum amine complex in zeolite HZSM-5 catalyst

被引:6
作者
van den Broek, ACM [1 ]
van Grondelle, J [1 ]
van Santen, RA [1 ]
机构
[1] Eindhoven Univ Technol, Schuit Inst Catalysis, Inorgan Chem & Catalysis Lab, NL-5600 MB Eindhoven, Netherlands
关键词
platinum; ammonia oxidation; water; ZSM-5; Pt(NH3)(4)](2+);
D O I
10.1023/A:1019066425124
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study it was found that [Pt(NH3)(4)]HZSM-5 is an active catalyst for the oxidation of ammonia at low temperature that, in contrast with other catalysts, becomes more active in the presence of water. Furthermore, the selectivity to nitrogen was found to increase when water is present.
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收藏
页码:79 / 82
页数:4
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