Mesoporous nanostructured Co3O4 derived from MOF template: a high-performance anode material for lithium-ion batteries

被引：276

作者：

Li, Chao ^{[1
]}

Chen, Taiqiang ^{[1
]}

Xu, Weijing ^{[1
]}

Lou, Xiaobing ^{[1
]}

Pan, Likun ^{[1
]}

Chen, Qun ^{[1
]}

Hu, Bingwen ^{[1
]}

机构：

[1] E China Normal Univ, Shanghai Key Lab Magnet Resonance, Engn Res Ctr Nanophoton & Adv Instrument, Dept Phys,Minist Educ, Shanghai 200062, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2015年 / 3卷 / 10期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; PROTON CONDUCTION; BINDER-FREE; STORAGE; GRAPHENE; CONVERSION; NANOCOMPOSITES; SEPARATION; NANOTUBES; ELECTRODE;

D O I：

10.1039/c4ta06914e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mesoporous nanostructured Co3O4 was prepared by the direct pyrolysis of a Co-based metal organic framework (MOF) template at a relatively low temperature rather than a high temperature. When tested as an anode material for lithium-ion batteries (LIBs), this porous Co3O4 exhibited a greatly enhanced performance of lithium storage. The capacity of the porous Co3O4 retained 913 mA h g(-1) after 60 cycles at a current rate of 200 mA g(-1). Excellent rate capability was also achieved. We also found out that the Co3O4 prepared from the MOF template at a relatively low temperature has better electrochemical performance than that prepared at high temperature.

引用

收藏

页码：5585 / 5591

页数：7

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