Crystal structure of mu(2)-hydridododecacarbonyltriosmium dioxooctafluoro-mu(2)-fluoroditungsten

被引：9

作者：

Crossman, MC ^{[1
]}

Fawcett, J ^{[1
]}

Hope, EG ^{[1
]}

Russell, DR ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,LEICS,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 514卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

osmium; tungsten; hydride; carbonyl; cluster; crystal structure;

D O I：

10.1016/0022-328X(95)06012-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Protonation of [Os-3(CO)(12)] occurs readily in anhydrous HF; the addition of WF6 gives a route to the title compound, [HOs3(CO)(12)][W2O2F9], which forms as triclinic crystals. The anion is a fluoride-bridged dimer, whilst the bridging hydride ligand in the carbonyl cluster cation has been located by difference Fourier techniques and the geometry of the carbonyl ligands.

引用

页码：87 / 91

页数：5

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