Carbon Materials for Lithium Sulfur Batteries-Ten Critical Questions

被引:351
作者
Borchardt, Lars [1 ]
Oschatz, Martin [2 ]
Kaskel, Stefan [1 ]
机构
[1] Tech Univ Dresden, Inst Inorgan Chem, Bergstr 66, D-01069 Dresden, Germany
[2] Univ Utrecht, Grp Inorgan Chem & Catalysis, Debye Inst Nanomat Sci, Univ Weg 99, NL-3584 CG Utrecht, Netherlands
关键词
batteries; lithium; secondary battery; shuttle mechanism; sulfur; X-RAY-DIFFRACTION; LI-S BATTERIES; DISCHARGE-CHARGE PROCESS; CARBIDE-DERIVED CARBONS; HIGH-PERFORMANCE; IN-SITU; CATHODE MATERIALS; POROUS CARBON; ELECTROCHEMICAL PERFORMANCE; LIQUID ELECTROLYTES;
D O I
10.1002/chem.201600040
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lithium-sulfur batteries are among the most promising electrochemical energy storage devices of the near future. Especially the low price and abundant availability of sulfur as the cathode material and the high theoretical capacity in comparison to state-of-the art lithium-ion technologies are attractive features. Despite significant research achievements that have been made over the last years, fundamental (electro-) chemical questions still remain unanswered. This review addresses ten crucial questions associated with lithium-sulfur batteries and critically evaluates cur-rent research with respect to them. The sulfur-carbon composite cathode is a particular focus, but its complex interplay with other hardware components in the cell, such as the electrolyte and the anode, necessitates a critical discussion of other cell components. Modern in situ characterisation methods are ideally suited to illuminate the role of each component. This article does not pretend to summarise all recently published data, but instead is a critical overview over lithium-sulfur batteries based on recent research findings.
引用
收藏
页码:7324 / 7351
页数:28
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