Amphiphilic Self-Assembly of an n-Type Nanotube

被引:177
作者
Shao, Hui [1 ]
Seifert, James [1 ]
Romano, Natalie C. [2 ,3 ]
Gao, Min [1 ]
Helmus, Jonathan J. [1 ]
Jaroniec, Christopher P. [1 ]
Modarelli, David A. [2 ,3 ]
Parquette, Jon R. [1 ]
机构
[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA
[2] Univ Akron, Dept Chem, Akron, OH 44325 USA
[3] Univ Akron, Ctr Laser & Opt Spect, Akron, OH 44325 USA
基金
美国国家科学基金会;
关键词
amino acids; bolaamphiphiles; nanotubes; self-assembly; semiconductors; TOPOCHEMICAL POLYMERIZATION; HET-S(218-289) PRION; MOLECULAR MATERIALS; AMYLOID FIBRILS; BUILDING-BLOCKS; POLYMERS; CONFORMATION; RESONANCE; DYNAMICS; VESICLES;
D O I
10.1002/anie.201003415
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mmm-stacks of donuts! A one-dimensional n-type nanotube was formed by stacking rings formed from the bolaamphiphilic self-assembly of 1,4,5,8-naphthalenetetracarboxylic acid diimide (NDI) with L-lysine headgroups (see picture). Solid-state NMR studies demonstrate the exceptional conformational homogeneity of the constituent molecules that make up the nanotubes. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:7688 / 7691
页数:4
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