Development of Agriculture Left-Overs: Fine Organic Chemicals from Wheat Hemicellulose-Derived Pentoses

被引：55

作者：

Martel, Frederic ^{[2
]}

Estrine, Boris ^{[2
]}

Plantier-Royon, Richard ^{[1
]}

Hoffmann, Norbert ^{[1
]}

Portella, Charles ^{[1
]}

机构：

[1] Univ Reims, Inst Chim Mol Reims, UFR Sci Exactes & Nat, CNRS,UMR 6229, F-51687 Reims 2, France

[2] Agroind Rech & Dev, F-51110 Pomacle, France

来源：

CARBOHYDRATES IN SUSTAINABLE DEVELOPMENT I: RENEWABLE RESOURCES FOR CHEMISTRY AND BIOTECHNOLOGY | 2010年 / 294卷

关键词：

D-Xylose; Enantiopure building-blocks; Furfural; L-Arabinose; Surfactants; TOTAL ASYMMETRIC-SYNTHESIS; DERIVATIVES NAKED SUGARS; ALPHA-GLUCOSIDASE INHIBITOR; C-NUCLEOSIDE SYNTHESIS; CHIRAL BUILDING-BLOCKS; DIELS-ALDER ADDITIONS; ENANTIOSELECTIVE SYNTHESIS; ENANTIOMERICALLY PURE; D-XYLOSE; EFFICIENT SYNTHESIS;

D O I：

10.1007/128_2010_54

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

This review is dedicated to wheat hemicelluloses and its main components D-xylose and L-arabinose as raw materials for fine organic chemistry. The context of the wheat agro-industry, its by-products, and extraction and hydrolysis of hemicelluloses to produce the pentoses are considered. The straightforward preparation of pentose-based surfactants, their properties, and their situation in the field of carbohydrate-based surfactants are addressed. Multistep transformations of pentoses are also described, first from a methodology point of view, with the aim of producing multifunctional enantiopure building-blocks, then considering targeted natural and/or bioactive products. Selected reactions of furfural, an important dehydration product of pentoses, are also presented.

引用

页码：79 / 115

页数：37

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