Synthesis and Coordination Properties of Nitrogen(I)-Based Ligands

被引：92

作者：

Bruns, Hans ^{[1
]}

Patil, Mahendra ^{[1
]}

Carreras, Javier ^{[1
]}

Vazquez, Arcadio ^{[1
]}

Thiel, Walter ^{[1
]}

Goddard, Richard ^{[1
]}

Alcarazo, Manuel ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 21期

关键词：

coordination chemistry; cyclopropenylylidenes; imines; nitrenes; nitrogen ligands; DIVALENT CARBON(0) CHEMISTRY; TRANSITION-METAL-COMPLEXES; BIS(IMIDAZOLIN-2-IMINE) LIGANDS; CRYSTAL-STRUCTURE; ADDUCTS; HEXAPHENYLCARBODIPHOSPHORANE; CARBODICARBENE; GENERATION; REACTIVITY; RHODIUM(I);

D O I：

10.1002/anie.200906168

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemical Equation Reprentation Cive me four: In contrast to typical imines, the central nitrogen atom in cyclopropenyl-derived carbeneimines (see example; C gray, N blue) can donate up to four electrons to form coordination complexes. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3680 / 3683

页数：4

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