Synthesis and Coordination Properties of Nitrogen(I)-Based Ligands

被引：91
作者：
Bruns, Hans [1 ]
Patil, Mahendra [1 ]
Carreras, Javier [1 ]
Vazquez, Arcadio [1 ]
Thiel, Walter [1 ]
Goddard, Richard [1 ]
Alcarazo, Manuel [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 21期
关键词：
coordination chemistry; cyclopropenylylidenes; imines; nitrenes; nitrogen ligands; DIVALENT CARBON(0) CHEMISTRY; TRANSITION-METAL-COMPLEXES; BIS(IMIDAZOLIN-2-IMINE) LIGANDS; CRYSTAL-STRUCTURE; ADDUCTS; HEXAPHENYLCARBODIPHOSPHORANE; CARBODICARBENE; GENERATION; REACTIVITY; RHODIUM(I);
D O I：
10.1002/anie.200906168
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chemical Equation Reprentation Cive me four: In contrast to typical imines, the central nitrogen atom in cyclopropenyl-derived carbeneimines (see example; C gray, N blue) can donate up to four electrons to form coordination complexes. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：3680 / 3683
页数：4
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