Catalytic reactions of gamma-valerolactone: A platform to fuels and value-added chemicals

被引：384

作者：

Yan, Kai ^{[1
]}

Yang, Yiyi ^{[1
]}

Chai, Jiajue ^{[1
]}

Lu, Yiran ^{[1
]}

机构：

[1] Brown Univ, Sch Engn, Providence, RI 02912 USA

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2015年 / 179卷

关键词：

Biomass; Conversion; gamma-Valerolactone; Fuels; Value-added chemicals; HIGHLY EFFICIENT HYDROGENATION; LEVULINIC ACID; LIGNOCELLULOSIC BIOMASS; SELECTIVE HYDROGENATION; ETHYL LEVULINATE; BIMETALLIC CATALYSTS; CARBOHYDRATE BIOMASS; PHASE HYDROGENATION; STEAM GASIFICATION; FURFURYL ALCOHOL;

D O I：

10.1016/j.apcatb.2015.04.030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Gamma-valerolactone (GVL), which is accessible from renewable lignocellulosic biomass, has been identified as one of the most promising platforms for the sustainable production of fuels and value-added chemicals. This review aims at recent advances in the catalytic production of GVL from biomass and further upgrading of GVL to fuels as well as value-added chemicals. The first part briefly reviews recent advances for the production of GVL from biomass. The second and third sections critically review and identify current technologies for the efficient production of GVL. The mechanism, different types of advanced homogeneous and heterogeneous catalysts employed have been compared and broadly categorized. Challenges and areas that need improvement are also highlighted in the corresponding area. The fourth section concentrates on potential applications and the upgrading of GVL to fuel additives, diesel fuels and value-added chemicals. The final section offers a summary and future perspective in the field. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：292 / 304

页数：13

共 127 条

[1] Analysis of Kinetics and Reaction Pathways in the Aqueous-Phase Hydrogenation of Levulinic Acid To Form γ-Valerolactone over Ru/C [J].