Carbon Dioxide Hydrogenation to Formic Acid by Using a Heterogeneous Gold Catalyst

被引：248

作者：

Preti, Debora ^{[1
]}

Resta, Claudio ^{[1
]}

Squarcialupi, Sergio ^{[2
]}

Fachinetti, Giuseppe ^{[1
]}

机构：

[1] Univ Pisa, Dipartimento Chim, I-56126 Pisa, Italy

[2] Chimet SpA, I-52041 Badia Al Pino, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 52期

关键词：

C1; chemistry; carbon dioxide; formic acid; gold catalysts; hydrogenation; STORAGE MATERIAL; GENERATION; DECOMPOSITION; COMPLEXES; ADDUCTS; CO2;

D O I：

10.1002/anie.201105481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

AUROlite, consisting of gold supported on titania (picture shows extrudates in a steel net cage), is a robust catalyst for the production of catalyst-free HCOOH/NEt 3 adducts from H 2, CO 2, and neat NEt 3. Pure HCOOH is freed from the adducts by amine exchange. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12551 / 12554

页数：4

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