Lewis acid promoted carbon-carbon bond cleavage of γ-silyloxy-β-hydroxy-α-diazoesters

被引：52

作者：

Draghici, Cristian ^{[1
]}

Brewer, Matthias ^{[1
]}

机构：

[1] Univ Vermont, Dept Chem, Burlington, VT 05405 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 12期

关键词：

D O I：

10.1021/ja801004d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclic gamma-silyloxy-beta-hydroxy-alpha-diazoesters undergo efficient rupture of the C beta-C gamma bond when treated with fin tetrachloride to provide tethered aldehyde ynoate products in high geld.

引用

页码：3766 / +

页数：3

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