Chemoselectivity in the Cu-catalyzed O-arylation of phenols and aliphatic alcohols

被引：36
|
作者：
Maiti, Debabrata [1 ,2 ]
机构：
[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India
[2] MIT, Dept Chem, Cambridge, MA 02139 USA
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 29期
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
COUPLING REACTIONS; N-ARYLATION; COPPER; INVENTION; LIGANDS; HALIDES; ARYL;
D O I：
10.1039/c1cc12694f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An orthogonal set of Cu-catalysts for the selective mono-arylation of alkyl aryl diols using aryl iodides is presented. Picolinic acid ligated copper catalyst provided phenol O-arylation only, while alkyl aryl ethers are generated by ligand-free copper catalyst in the presence of 2 equivalents NaOt-Bu.
引用
收藏
页码：8340 / 8342
页数：3
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