Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen

被引：24

作者：

Beier, Petr ^{[1
]}

Pastyrikova, Tereza ^{[1
]}

机构：

[1] Acad Sci Czech Republic, Inst Organ Chem & Biochem, CR-16610 Prague, Czech Republic

来源：

TETRAHEDRON LETTERS | 2011年 / 52卷 / 34期

关键词：

Pentafluorosulfanyl group; Vicarious nucleophilic substitution; Hydroxylation; HYPERVALENT SULFUR FLUORIDES; PENTAFLUORIDES;

D O I：

10.1016/j.tetlet.2011.06.011

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Para- and meta-nitro-(pentafluorosulfanyl)benzenes react with anions of cumyl hydroperoxide in the presence of t-BuOK in liquid ammonia to form nitro-(pentafluorosulfanyl)phenols. Their reduction with hydrogen in the presence of Raney-Nickel provides amino-(pentafluorosulfanyl)phenols. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：4392 / 4394

页数：3

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