Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen

被引：24
|
作者：
Beier, Petr [1 ]
Pastyrikova, Tereza [1 ]
机构：
[1] Acad Sci Czech Republic, Inst Organ Chem & Biochem, CR-16610 Prague, Czech Republic
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 34期
关键词：
Pentafluorosulfanyl group; Vicarious nucleophilic substitution; Hydroxylation; HYPERVALENT SULFUR FLUORIDES; PENTAFLUORIDES;
D O I：
10.1016/j.tetlet.2011.06.011
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Para- and meta-nitro-(pentafluorosulfanyl)benzenes react with anions of cumyl hydroperoxide in the presence of t-BuOK in liquid ammonia to form nitro-(pentafluorosulfanyl)phenols. Their reduction with hydrogen in the presence of Raney-Nickel provides amino-(pentafluorosulfanyl)phenols. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4392 / 4394
页数：3
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