X-ray photoelectron spectroscopy analysis on surface modification of Konjac glucomannan membrane by nitrogen plasma treatment

被引:24
作者
Pang, Jie [1 ]
Jian, Wenjie [1 ,2 ]
Wang, Liangyu [3 ]
Wu, Chunhua [1 ]
Liu, Yanan [1 ]
He, Jing [1 ]
Tang, Xingfu [4 ]
机构
[1] Fujian Agr & Forestry Univ, Coll Food Sci, Fuzhou 350002, Peoples R China
[2] Xiamen Ocean Vocat Coll, Dept Biol Technol, Xiamen 361012, Peoples R China
[3] Fujian Normal Univ, Biol & Chem Engn Dept, Fuqing Branch, Fuqing 350300, Peoples R China
[4] Fujian Prov Dept Ocean & Fisheries, Fuzhou 35000, Peoples R China
基金
中国国家自然科学基金;
关键词
X-ray photoelectron spectroscopy; Nitrogen plasma; Konjac glucomannan; Modification; Surface; CELLULOSE;
D O I
10.1016/j.carbpol.2011.12.013
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In order to improve the surface property of Konjac glucomannan (KGM) film, the nitrogen plasma modification was carried out using ion beam injection machine. The surface atomic composition was evaluated by X-ray photoelectron spectroscopy analysis afterward. It was observed that the atomic concentration ratio of wO/wC increased using plasma treatment. The molecular chain degraded and acetyl was partly removed. Hydroxyl was partly replaced by primary amide group. Generation of new functionality groups suggested that plasma treatment might be an effective means to modify the physical property of KGM film. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:369 / 372
页数:4
相关论文
共 12 条
[1]  
[Anonymous], 1992, HIGH RESOLUTION XPS, DOI DOI 10.1002/ADMA.19930051035
[2]   Surface modification of polyester to produce a bacterial cellulose-based vascular prosthetic device [J].
Charpentier, Paul A. ;
Maguire, Anne ;
Wan, Wan-kei .
APPLIED SURFACE SCIENCE, 2006, 252 (18) :6360-6367
[3]  
Ding CM, 2007, SPECTROSC SPECT ANAL, V27, P1185
[4]  
Jian WJ, 2010, CHINESE J STRUC CHEM, V29, P1084
[5]  
Jian WJ, 2010, CHINESE J STRUC CHEM, V29, P543
[6]   Molecular simulation of the complex of konjac glucomannan-borate in water [J].
Jian, Wenjie ;
Zeng, Yuan ;
Xiong, Hejian ;
Pang, Jie .
CARBOHYDRATE POLYMERS, 2011, 85 (02) :452-456
[7]   Surface functionalization of cellulose by grafting oligoether chains [J].
Ly, El Hadji Babacar ;
Bras, Julien ;
Sadocco, Patrizia ;
Belgacem, Mohamed Naceur ;
Dufresne, Alain ;
Thielemans, Wim .
MATERIALS CHEMISTRY AND PHYSICS, 2010, 120 (2-3) :438-445
[8]   Plasma-enhanced synthesis of maltodextrin-polydimethylsiloxane graft copolymers [J].
Ma, YC ;
Manolache, S ;
Sarmadi, M ;
Denes, F .
JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 80 (08) :1120-1129
[9]  
Pang J, 2003, CHINESE J STRUC CHEM, V22, P633
[10]  
Vesel A, 2008, INFORM MIDEM, V38, P257