Plasma thermal conversion of bio-oil for hydrogen production

被引:9
作者
Guenadou, David [3 ]
Lorcet, Helene [3 ]
Peybernes, Jean [3 ]
Catoire, Laurent [1 ]
Osmont, Antoine [2 ]
Goekalp, Iskender [4 ]
机构
[1] Ecole Natl Super Tech Avancees ENSTA ParisTech, F-75739 Paris 15, France
[2] Commissariat Energie Atom & Energies Alternat CEA, F-46500 Gramat, France
[3] Commissariat Energie Atom & Energies Alternat CEA, DEN DTN STPA LPC, F-13108 St Paul Les Durance, France
[4] CNRS, INSIS, ICARE, F-45071 Orleans 2, France
关键词
bio-oil; hydrogen; plasma; thermal process; FAST PYROLYSIS;
D O I
10.1002/er.1894
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Numerous processes exist or are proposed for the energetic conversion of biomass. The use of thermal plasma is proposed in the frame of the GALACSY project for the conversion of bio-oil to hydrogen and carbon monoxide. For this purpose, an experimental apparatus has been built. The feasibility of this conversion at very high temperature, as encountered in thermal plasma, is examined both experimentally and numerically. This zero dimensional study tends to show that a high temperature (around 2500K or above) is needed to ensure a high yield of hydrogen (about 50mol%) and about 95 mol% of CO+H2. Predicted CO?+?H2 yield and CO/H2 ratio are consistent with measurements. It is also expected that the formation of particles and tars is hampered. Thermodynamic data of selected bio-oil components are provided in the CHEMKINNASA format. Copyright (C) 2011 John Wiley & Sons, Ltd.
引用
收藏
页码:409 / 414
页数:6
相关论文
共 17 条
  • [1] [Anonymous], 45
  • [2] Thermochemistry of Compounds Formed during Fast Pyrolysis of Lignocellulosic Biomass
    Catoire, Laurent
    Yahyaoui, Mohammed
    Osmont, Antoine
    Goekalp, Iskender
    [J]. ENERGY & FUELS, 2008, 22 (06) : 4265 - 4273
  • [3] Plasma Thermal Conversion of Methane to Acetylene
    Fincke J.R.
    Anderson R.P.
    Hyde T.
    Detering B.A.
    Wright R.
    Bewley R.L.
    Haggard D.C.
    Swank W.D.
    [J]. Plasma Chemistry and Plasma Processing, 2002, 22 (1) : 105 - 136
  • [4] Guenadou D, 2009, 17 EUR BIOM C HAMB
  • [5] Lorcet H, 2009, THESIS U LIMOGES FRA
  • [6] Lutz AE, EQUIL: A Chemkin implementation of stanjan, 1 for Computing Chemical Equilibria
  • [7] Non-catalytic partial oxidation of bio-oil to synthesis gas for distributed hydrogen production
    Marda, Jonathan R.
    DiBenedetto, Joelle
    McKibben, Shannon
    Evans, Robert J.
    Czernik, Stefan
    French, Richard J.
    Dean, Anthony M.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (20) : 8519 - 8534
  • [8] Meier D, 1999, FAST PYROLYSIS BIOMA
  • [9] Milne TA, 1998, TP57025357 NREL
  • [10] Pyrolysis of wood/biomass for bio-oil: A critical review
    Mohan, Dinesh
    Pittman, Charles U., Jr.
    Steele, Philip H.
    [J]. ENERGY & FUELS, 2006, 20 (03) : 848 - 889