The Diphosphorus Complex [Cp2Mo2(CO)4(η2-P2)] as a Building Block for the Synthesis of Mixed-Hybrid Coordination Polymers

被引：15

作者：

Moussa, Mehdi Elsayed ^{[1
]}

Attenberger, Bianca ^{[1
]}

Fleischmann, Martin ^{[1
]}

Schreiner, Andrea ^{[1
]}

Scheer, Manfred ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 28期

基金：

欧洲研究理事会;

关键词：

Self-assembly; Phosphorus; Hybrid polymers; 2,2 '-Bipyrimidine; Molybdenum; ONE-DIMENSIONAL POLYMERS; STRUCTURAL VARIATION; MAGNETIC-PROPERTIES; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; NMR-SPECTROSCOPY; GAS-ADSORPTION; LIGANDS; CONSTRUCTION; MACROCYCLES;

D O I：

10.1002/ejic.201600895

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The three-component reaction of the tetrahedral diphosphorus complex [Cp2Mo2(CO)(4)(eta(2)-P-2)] (1), with Ag[BF4] (2) in the presence of 2,2'-bipyrimidine (3) leads to the formation of the two novel two-dimensional networks 4 and 5. Compound 4 is a new two-dimensional organometallic-organic hybrid polymer, while derivative 5 represents a unique two-dimensional organometallic-inorganic-organic hybrid polymer. These results show the possibility of synthesizing a new class of coordination polymers, which could not be obtained from two-component reactions with organic molecules in addition of metal ions.

引用

页码：4538 / 4541

页数：4

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