The Diphosphorus Complex [Cp2Mo2(CO)4(η2-P2)] as a Building Block for the Synthesis of Mixed-Hybrid Coordination Polymers

被引：15
|
作者：
Moussa, Mehdi Elsayed [1 ]
Attenberger, Bianca [1 ]
Fleischmann, Martin [1 ]
Schreiner, Andrea [1 ]
Scheer, Manfred [1 ]
机构：
[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 28期
基金：
欧洲研究理事会;
关键词：
Self-assembly; Phosphorus; Hybrid polymers; 2,2 '-Bipyrimidine; Molybdenum; ONE-DIMENSIONAL POLYMERS; STRUCTURAL VARIATION; MAGNETIC-PROPERTIES; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; NMR-SPECTROSCOPY; GAS-ADSORPTION; LIGANDS; CONSTRUCTION; MACROCYCLES;
D O I：
10.1002/ejic.201600895
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The three-component reaction of the tetrahedral diphosphorus complex [Cp2Mo2(CO)(4)(eta(2)-P-2)] (1), with Ag[BF4] (2) in the presence of 2,2'-bipyrimidine (3) leads to the formation of the two novel two-dimensional networks 4 and 5. Compound 4 is a new two-dimensional organometallic-organic hybrid polymer, while derivative 5 represents a unique two-dimensional organometallic-inorganic-organic hybrid polymer. These results show the possibility of synthesizing a new class of coordination polymers, which could not be obtained from two-component reactions with organic molecules in addition of metal ions.
引用
收藏
页码：4538 / 4541
页数：4
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