The influence of processing parameters on the structural and mechanical properties of drawn polypropylene fibres: A factorial design approach

This article reports a study of multi-stage polypropylene fiber drawing (stretching) as a continuous, but independent stage of the overall fiber-forming process. The fibers were drawn according to a factorial experimental design, once appropriate spinning conditions had been devised. The structures of the drawn fibers were studied using wide-angle X-ray diffraction and birefringence measurements. In addition, the fibers were characterized with respect to filament tenacity, elongation to break, specific secant modulus, and extent of shrinkage at 130 degrees C. All these properties were quantitatively assessed as responses to nine specially selected process control parameters in the drawing equipment. For every property analyzed, the temperatures of the hot plates in the draw frame were found to exert no significant influence, whereas the temperatures of the initial rollers were in most cases significant. Furthermore, the speed of the final roller also played an influential role, and a number of interactions between process parameters were identified as significant. Explanations are advanced for the parts played by significant process parameters on the properties of the drawn fibers. The article also demonstrates the advantages of factorial experimental design in determining correct settings for process parameters to give drawn fibers with the properties desired. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012