Electrical conductivity improvement of Fe doped ZnO nanopowders

被引:100
作者
Saadi, H. [1 ]
Rhouma, F. I. H. [2 ]
Benzarti, Z. [1 ]
Bougrioua, Z. [3 ,4 ]
Guermazi, S. [5 ]
Khirouni, K. [6 ]
机构
[1] Univ Sfax, Fac Sci Sfax, Dept Phys, Lab Multifunct Mat & Applicat LaMMA, Soukra Rd Km 3-5 BP 1171, Sfax 3000, Tunisia
[2] Univ Tunis El Manar, Ctr Res & Technol Energy, Lab Nanomat & Syst Renewable Energies LANSER, BP 95, Hammam Lif 2050, Tunisia
[3] CNRS, Inst Elect Microelect & Nanotechnol IEMN, Ave Poincare, F-59652 Villeneuve Dascq, France
[4] Univ Sci & Technol Lille 1, Ave Poincare, F-59652 Villeneuve Dascq, France
[5] Univ Sfax, Fac Sci Sfax, Res Unit Phys Insulators & Semi Insulator Mat, Soukra Rd Km 3-5,BP 1171, Sfax 3000, Tunisia
[6] Univ Gabes, Fac Sci Gabes, Lab Phys Mat & Nanomat Appl Environm LaPhyMNE, Gabes 6072, Tunisia
关键词
ZnO nanopowders; Fe doping; Co-precipitation method; Optical properties; Conductivity; ROOM-TEMPERATURE FERROMAGNETISM; MAGNETIC-PROPERTIES; DIELECTRIC-PROPERTIES; OPTICAL-PROPERTIES; THIN-FILMS; ZINC-OXIDE; PHYSICAL INVESTIGATIONS; RAPID SYNTHESIS; NANOPARTICLES; NI;
D O I
10.1016/j.materresbull.2020.110884
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The chemical co-precipitation process was used for the synthesis of Fe-doped ZnO nanopowders (ZnO:Fe) with varying doping concentrations from 0% to 10 %. Doping with iron caused significant alterations in the physical properties of ZnO nanopowders. The XRD analysis revealed that Fe introduction forms a secondary phase of spinel ZnFe2O4 for doping concentration higher than 1%. The average crystallite size was proven to decrease with the increase in Fe concentration. SEM images showed the formation of spherical nanoparticles, where the average grain size decreased with doping. The Fe incorporation into the ZnO host lattice was also confirmed by FTIR and Raman spectroscopy. The optical properties were strongly influenced by Fe doping. The dielectric parameters were subsequently investigated as a function of frequency and composition. The observed dielectric dispersion was interpreted on the basis of Maxwell-Wagner interfacial model and Koops phenomenological theory. Overall, Fe doping improved the electrical conductivity of ZnO nanopowders.
引用
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页数:12
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