Demethylation of the [Me3Sn(PhN2O2)]4 tetramer into dimeric [Me2Sn(PhN2O2)2]2:: a thermally induced methyl-transfer between supramolecules

被引：6

作者：

Deák, A ^{[1
]}

Tárkányi, G ^{[1
]}

机构：

[1] Hungarian Acad Sci, Inst Struct Chem, Chem Res Ctr, H-1525 Budapest, Hungary

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 32期

关键词：

D O I：

10.1039/b506728f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The single crystals of tetrameric [Me3Sn(PhN2O2)](4) (1) supramolecule demethylates into single crystals of [Me2Sn(PhN2O2)(2)](2) dimer (2) and volatile Me4Sn, as a result of a crystal-to-crystal supramolecular structural transformation, which occurs upon heating and it is accompanied by a significant change of the molecular and crystal structures.

引用

页码：4074 / 4076

页数：3

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