Identification of dielectric and magnetic properties of core shell ZnTiO3/CoFe2O4nanocomposites

被引:52
作者
Abou Hammad, Ali B. [1 ]
Darwish, Abdelfattah G. [2 ]
El Nahrawy, Amany M. [1 ]
机构
[1] Natl Res Ctr, Phys Res Div, Dept Solid State Phys, 33 El Bohouth St, Cairo 12622, Egypt
[2] Natl Res Ctr, Phys Res Div, Microwave Phys & Dielect Dept, 33 El Bohouth St, Cairo 12622, Egypt
来源
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2020年 / 126卷 / 07期
关键词
ZnTiO3; CoFe(2)O(4)core shell; Sol-gel method; Perovskite nanoparticles; Magnetic and dielectric properties; IMPEDANCE SPECTROSCOPY; COFE2O4; NANOPARTICLES; GEL; NANOCOMPOSITES; TEMPERATURE; DELIVERY; DRUG; NANOSTRUCTURE; CONDUCTIVITY; PERFORMANCE;
D O I
10.1007/s00339-020-03679-z
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electromagnetic core shell nanocomposites (1 - x) ZnTiO3/(x) CoFe(2)O(4)were prepared successfully through sol-gel procedures, where (x similar to 0, 5, 10 and 15 wt%). The end product powders were identified through XRD, SEM, and TEM. The XRD results prove the presence of ZnTiO(3)and CoFe2O4, while the SEM graph confirms the core-shell nanostructure. The dielectric properties such as dielectric constant (epsilon '), loss tangent tan(delta), dielectric modulusM ' andM '', and ac conductivity (sigma) are measured in the frequency range 0.1-10(7) Hz. The dielectric properties show a dependence behavior on the variation of CoFe(2)O(4)content in the core-shell composite. CoFe2O4@ZnTiO(3)nanocomposites manifest striking enhancement on dielectric properties compared to ZnTiO3. The dielectric permittivity (e ') increases from 204 to 415 at low frequency with increasing the CFO content from zero to 15 wt%. The Loss tangent tan (delta) of the electromagnetic nanocomposite has a very tiny value of 3.8 x 10(-3)in the high-frequency range proving a very high-quality factor (Q = nu x 1/tan (delta) similar to 2 x 10(9)at 10(7) Hz.M" shows a peak that differentiates between the long-range hopping and the localized motion of the charge carriers. The conductivity of the electromagnetic composite is released from hopping charge carriers over the whole frequency range compared to CoFe2O4. The improvement of the micro capacitor due to the interfacial polarization enhances the dielectric characterization of CoFe2O4@ZnTiO3. The electromagnetic samples show a presence of magnetic order, in which the saturation magnetization of the electromagnetic samples increases from 0.113 to 9.35 emu/g with increasing CoFe(2)O(4)concentration from 5 to 15 wt%.
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页数:12
相关论文
共 69 条
[1]   A novel electromagnetic biodegradable nanocomposite based on cellulose, polyaniline, and cobalt ferrite nanoparticles [J].
Abou Hammad, A. B. ;
Abd El-Azizb, M. E. ;
Hasanin, M. S. ;
Kamel, S. .
CARBOHYDRATE POLYMERS, 2019, 216 :54-62
[2]   Two step synthesis, electromagnetic and microwave absorbing properties of FeCo@C core-shell nanostructure [J].
Afghahi, S. S. S. ;
Shokuhfar, A. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2014, 370 :37-44
[3]   Structural, magnetic and Raman study of CoFe2O4@C core-shell nanoparticles [J].
Bakhshi, Hamed ;
Shokuhfar, Ali ;
Afghahi, Seyyed Salman Seyyed .
CERAMICS INTERNATIONAL, 2015, 41 (09) :10736-10744
[4]   Effects of Al2O3 on dielectric properties of core-shell Ba0.7Sr0.3Ti0.9925Tm0.0103@Al2O3 ceramics [J].
Ban, Huiyun ;
Fan, Yongzhe ;
Zhao, Xue ;
Du, An ;
Ma, Ruina ;
Chen, Kaixuan ;
Cao, Xiaoming ;
Li, Xuan .
MATERIALS CHEMISTRY AND PHYSICS, 2020, 241
[5]  
Battisha IK, 2007, INDIAN J PURE AP PHY, V45, P441
[6]   Composite BNT-BT0.08/CoFe2O4 with core-shell nanostructure for piezoelectric and ferromagnetic applications [J].
Cernea, M. ;
Vasile, B. S. ;
Ciuchi, I. V. ;
Surdu, V. A. ;
Bartha, C. ;
Iuga, A. ;
Galizia, P. ;
Galassi, C. .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2019, 240 :7-15
[7]   CoFe2O4 magnetic ceramic derived from gel and densified by spark plasma sintering [J].
Cernea, Mann ;
Galizia, Pietro ;
Ciuchi, Ioana ;
Aldica, Gheorghe ;
Mihalache, Valentina ;
Diamandescu, Lucian ;
Galassi, Carmen .
JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 656 :854-862
[8]   Synthesis, Structural and Electrical Properties of BNT-BTCe@SiO2 Core-Shell Heterostructure [J].
Cernea, Marin ;
Vasile, Bogdan Stefan ;
Ciuchi, Ioana Veronica ;
Iuga, Alin ;
Alexandrescu, Elvira ;
Pintea, Jana ;
Galassi, Carmen .
SCIENCE OF ADVANCED MATERIALS, 2015, 7 (11) :2297-2305
[9]   Iron oxide nanoparticles as a drug delivery vehicle for MRI monitored magnetic targeting of brain tumors [J].
Chertok, Beata ;
Moffat, Bradford A. ;
David, Allan E. ;
Yu, Faquan ;
Bergemann, Christian ;
Ross, Brian D. ;
Yang, Victor C. .
BIOMATERIALS, 2008, 29 (04) :487-496
[10]   Impedance spectroscopy and conductivity studies in SrBi2(Ta1-xWx)2O9 ferroelectric ceramics [J].
Coondoo, Indrani ;
Panwar, Neeraj ;
Tomar, Amit ;
Jha, A. K. ;
Agarwal, S. K. .
PHYSICA B-CONDENSED MATTER, 2012, 407 (24) :4712-4720