On the way to a new class of catalysts - High-valent transition-metal complexes that catalyze reductions

被引：36
|
作者：
Thiel, WR [1 ]
机构：
[1] Tech Univ Chemnitz, Inst Chem, D-09111 Chemnitz, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 44期
关键词：
aldehydes; homogeneous catalysis; hydrosilylation; oxo ligands; rhenium;
D O I：
10.1002/anie.200301685
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Surprise! Owning to its rheunium (v) center, which bears two terminal oxo ligands, [Rel(O)2(PPH3)2] appears at first glance to be an oxygen-transfer reagent. The complex is, however, a novel catalyst for a reduction: the hydrosilylation of aldehydes and ketones.
引用
收藏
页码：5390 / 5392
页数：3
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