Electrochemical recognition and immobilization of uranyl ions by polypyrrole film doped with calix[6]arene

被引：36

作者：

Kaneto, K ^{[1
]}

Bidan, G

机构：

[1] Kyushu Inst Technol, Dept Comp Sci & Elect, Iizuka, Fukuoka 820, Japan

[2] CEA Grenoble, DRFMC SI3M, UMR 5879, Electrochim Mol Lab, F-38054 Grenoble 09, France

来源：

THIN SOLID FILMS | 1998年 / 331卷 / 1-2期

关键词：

uranyl ion; recognition; conducting polymers; calixarenes; immobilization; polypyrrole;

D O I：

10.1016/S0040-6090(98)00930-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Sensing and immobilization of uranyl ions have been studied by electrochemical methods using modified electrodes by a conducting polymer. polypyrrole doped with calixarenes. Cyclic voltammograms are examined for various combinations of electrodes and electrolytes at various pHs. Redox peaks. that are characteristics of uranyl ions, are enhanced by the modified electrode with polypyrrole doped by calix[6]arene-p-hexasulphonate. The modified electrode is found to immobilize uranyl ions by special treatments of the modified electrode. The results are discussed with the ability of high selectivity and immobilization of calixarene for uranyl ions. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：272 / 278

页数：7

共 10 条

[1] ELECTROREDUCTION OF URANYL-ION IN AQUEOUS CALCIUM NITRATE SOLUTIONS [J].

BANSAL, NP ;

PLAMBECK, JA .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1981, 59 (10) :1515-1520

[2] Electrode modified by sulfonated calixarenes immobilized into a polypyrrole film: A step towards new ion-sensitive layers [J].

Bidan, G ;

Niel, MA .

SYNTHETIC METALS, 1997, 84 (1-3) :255-256

[3] RESPONSE OF CHEMOMECHANICAL DEFORMATION IN POLYANILINE FILM ON VARIETY OF ANIONS [J].

KANETO, K ;

KANEKO, H ;

TAKASHIMA, W .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1995, 34 (7A) :L837-L840

[4] CHEMISTRY OF AQUEOUS URANIUM(V) SOLUTIONS .1. PREPARATION AND PROPERTIES - ANALOGY BETWEEN URANIUM(V), NEPTUNIUM(V) AND PLUTONIUM(V) [J].

KRAUS, KA ;

NELSON, F ;

JOHNSON, GL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (07) :2510-2517

[5] PREPARATION OF A DNA MATRIX VIA AN ELECTROCHEMICALLY DIRECTED COPOLYMERIZATION OF PYRROLE AND OLIGONUCLEOTIDES BEARING A PYRROLE GROUP [J].

LIVACHE, T ;

ROGET, A ;

DEJEAN, E ;

BARTHET, C ;

BIDAN, G ;

TEOULE, R .

NUCLEIC ACIDS RESEARCH, 1994, 22 (15) :2915-2921

[6]

Mendes-Viegas F., 1994, BIOSENS BIOELECTRON, V9, P219

[7] SELECTIVE ADSORPTION OF UO22+ TO A POLYMER RESIN IMMOBILIZING CALIXARENE-BASED URANOPHILES [J].

SHINKAI, S ;

KAWAGUCHI, H ;

MANABE, O .

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1988, 26 (09) :391-396

[8] MOLECULAR DESIGN OF CALIXARENE-BASED URANOPHILES WHICH EXHIBIT REMARKABLY HIGH-STABILITY AND SELECTIVITY [J].

SHINKAI, S ;

KOREISHI, H ;

UEDA, K ;

ARIMURA, T ;

MANABE, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (21) :6371-6376

[9] VERY CONVENIENT AND EFFICIENT PURIFICATION METHOD FOR FULLERENE (C-60) WITH 5,11,17,23,29,35,41,47-OCTA-TERT-BUTYLCALIX[8]ARENE-49,50,51,52,53,54,55,56-OCTOL [J].

SUZUKI, T ;

NAKASHIMA, K ;

SHINKAI, S .

CHEMISTRY LETTERS, 1994, (04) :699-702

[10] ELECTROCHEMICAL-BEHAVIOR AND PRECONCENTRATION OF URANYL(VI) AT NAFION-COATED GLASSY-CARBON ELECTRODES [J].

UGO, P ;

BALLARIN, B ;

DANIELE, S ;

MAZZOCCHIN, GA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 324 (1-2) :145-159

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