Hydrogen induced phase transitions in amorphous alloys

被引：3

作者：

Somenkov, V. A. ^{[1
]}

Agafonov, S. S. ^{[1
]}

Glazkov, V. P. ^{[1
]}

Syrykh, G. F. ^{[1
]}

Verbetsky, V. N. ^{[2
]}

Yaropolov, Yu. L. ^{[2
]}

机构：

[1] RRC Kurchatov Inst, Moscow 123182, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow, Russia

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2011年 / 36卷 / 01期

关键词：

Neutron diffraction; Amorphous alloys; Phase transition; SUPERCONDUCTIVITY; MICROSAMPLES; SYSTEMS;

D O I：

10.1016/j.ijhydene.2010.07.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogen induced structure transformations in amorphous alloys ZrPd, ZrRh and ZrRhBe were studied by neutron and X-ray-diffraction technique under gas pressure up to 2 kbar. It was shown that the amorphous alloy Zr(0.7)Pd(0.3) which was hydrogenated at temperature below the temperature of crystallization decomposes into metastable hyper-stoichiometric Pd-hydride with bcc lattice and amorphous hypo-stoichiometric Zr-hydride. The polyamorphous transition (transition between the amorphous phases) was reversible while the formation of metastable phase was not. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.

引用

页码：1209 / 1211

页数：3

共 13 条

[1] Powder diffractometer for microsamples at the Kurchatov Synchrotron Radiation Source [J].

Aksenov, V. L. ;

Glazkov, V. P. ;

Kichanov, S. E. ;

Pogoreliy, D. K. ;

Podurets, K. M. ;

Somenkov, V. A. ;

Savenko, B. N. ;

Yakovenko, E. V. .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2007, 575 (1-2) :266-268

[2] THE PD-PT-H SYSTEM - PHASE-TRANSFORMATIONS AT HIGH-PRESSURE AND SUPERCONDUCTIVITY [J].

ANTONOV, VE ;

ANTONOVA, TE ;

BELASH, IT ;

PONYATOVSKII, EG ;

RASHUPKIN, VI .

PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1983, 78 (01) :137-146

[3] SUPERCONDUCTIVITY AND ATOMIC ORDERING OF PD-CU-H SOLID-SOLUTIONS [J].

ANTONOV, VE ;

ANTONOVA, TE ;

BELASH, IT ;

MALYSHEV, VY ;

RASHUPKIN, VI .

PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1984, 81 (02) :K185-K190

[4]

BABUSHKINA NA, COMMUNICATION

[5]

BARANOVSKII B, 1981, HYDROGEN METALS, V2, P190

[6]

BOLTALINA OV, 2003, ZAVODSKAYA LAB RUSSI, V69, P29

[7] SUPERPOSITIONAL MANY-DETECTOR SYSTEMS AND NEUTRON-DIFFRACTION OF MICROSAMPLES [J].

GLAZKOV, VP ;

NAUMOV, IV ;

SOMENKOV, VA ;

SHILSHTEIN, SS .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 1988, 264 (2-3) :367-374

[8] HYDROGEN CAUSED ORDERING IN PDAG ALLOY [J].

IRODOVA, AV ;

GLAZKOV, VP ;

SOMENKOV, VA ;

ANTONOV, VE ;

PONYATOVSKY, EG .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE NEUE FOLGE, 1989, 163 :53-57

[9] Hydrogen-induced segregation in Pd-Pt alloys [J].

Noh, H ;

Flanagan, TB ;

Sakamoto, Y .

JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 231 (1-2) :10-14

[10]

Semiletov SA, 1980, KRISTALLOGRAFIYA, V25, P1290

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