The standard molar enthalpies of formation of some alkyladamantanes

被引:23
作者
Melkhanova, SV
Pimenova, SM
Kolesov, VP [1 ]
Pimerzin, AA
Sarkisova, VS
机构
[1] Moscow State Univ, Dept Chem, Moscow 119899, Russia
[2] Samara State Tech Univ, Samara 443010, Russia
关键词
thermochemistry; calorimetry; enthalpies of combustion; enthalpies of formation; alkyladamantanes;
D O I
10.1006/jcht.2000.0691
中图分类号
O414.1 [热力学];
学科分类号
摘要
The standard massic energies of combustion of three alkyl-derivative of adamantane were measured at T = 298.15 K by static-bomb combustion calorimetry. The standard molar enthalpies of formation in the liquid and gaseous states were obtained from these data. The enthalpies of some reactions of isomerization were calculated from the equilibrium study and compared with the results of calorimetric measurements. (C) 2000 Academic Press.
引用
收藏
页码:1311 / 1317
页数:7
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