Metal-Organic Frameworks as Platforms for Catalytic Applications

被引：1437

作者：

Jiao, Long ^{[1
]}

Wang, Yang ^{[1
]}

Jiang, Hai-Long ^{[1
]}

Xu, Qiang ^{[2
,3
]}

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Collaborat Innovat Ctr Suzhou Nanosci & Technol, Dept Chem,CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China

[2] Natl Inst Adv Ind Sci & Technol, Res Inst Electrochem Energy, 1-8-31 Midorigaoka, Ikeda, Osaka 5638577, Japan

[3] Kyoto Univ, AIST, Chem Energy Mat Open Innovat Lab ChEM OIL, Sakyo Ku, Kyoto 6068501, Japan

来源：

ADVANCED MATERIALS | 2018年 / 30卷 / 37期

关键词：

electrocatalysis; heterogeneous catalysis; metal-organic frameworks; photocatalysis; PHOTOCATALYTIC CO2 REDUCTION; POROUS COORDINATION POLYMER; SELECTIVE AEROBIC OXIDATION; CARBON-DIOXIDE REDUCTION; POT TANDEM CATALYSIS; PORE-SPACE PARTITION; HIGH-SURFACE-AREA; HIGHLY EFFICIENT; OXYGEN REDUCTION; ELECTROCHEMICAL REDUCTION;

D O I：

10.1002/adma.201703663

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks (MOFs), also called porous coordination polymers, represent a class of crystalline porous materials built from organic linkers and metal ions/clusters. The unique features of MOFs, including structural diversity and tailorability as well as high surface area, etc., enable them to be a highly versatile platform for potential applications in many fields. Herein, an overview of recent developments achieved in MOF catalysis, including heterogeneous catalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided. The active sites involved in the catalysts are particularly emphasized. The challenges, future trends, and prospects associated with MOFs and their related materials for catalysis are also discussed.

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页数：23

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