Photocatalytic behavior of PdCl2-modified nanostructured AgI/TiO2 photocatalyst

被引:5
作者
He Kefeng [1 ]
Zhu Kan [1 ]
Chen Wanping [1 ]
机构
[1] Wuhan Univ, Sch Phys & Technol, Key Lab Artificial Micro & Nanostruct, Minist Educ, Wuhan 430072, Peoples R China
来源
RARE METALS | 2011年 / 30卷
关键词
nanocomposite; TiO2; photocatalyst; TIO2; POWDERS; TITANIA; DEGRADATION; OXIDATION;
D O I
10.1007/s12598-011-0254-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanostructured AgI/TiO2 photocatalyst was synthesized through deposition-precipitation using AgNO3, KI and Ti(OBU)(4). Then the photocatalyst was further treated by PdCl2 solution, which resulted in a color change from yellow to green and PdCl2 reacted with AgI as indicated by X-ray diffraction analyses. The diffusive reflectance UV-vis spectroscopy of this modified photocatalyst shows a remarkable enhancement of the absorption intensity in the range of visible light. As nanostructured AgI/TiO2 shows a considerable visible light photocatalytic activity for the photodegradation of methylene blue, PdCl2-modified AgI/TiO2 exhibits a much larger visible light photocatalytic activity for the photodegradation of methylene blue.
引用
收藏
页码:131 / 134
页数:4
相关论文
共 16 条
[1]   The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation [J].
Anpo, M ;
Takeuchi, M .
JOURNAL OF CATALYSIS, 2003, 216 (1-2) :505-516
[2]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[3]   Room temperature visible light oxidation of CO by high surface area rutile TiO2-supported metal photocatalyst [J].
Bosc, Florence ;
Ayral, Andre ;
Keller, Nicolas ;
Keller, Valerie .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2007, 69 (3-4) :133-137
[4]   Enhanced nitrogen doping in TiO2 nanoparticles [J].
Burda, C ;
Lou, YB ;
Chen, XB ;
Samia, ACS ;
Stout, J ;
Gole, JL .
NANO LETTERS, 2003, 3 (08) :1049-1051
[5]  
Gao L., 2002, NANOSTRUCTURED TIO2
[6]   Carbon-doped anatase TiO2 powders as a visible-light sensitive photocatalyst [J].
Irie, H ;
Watanabe, Y ;
Hashimoto, K .
CHEMISTRY LETTERS, 2003, 32 (08) :772-773
[7]   Highly efficient visible-light-induced photocatalytic activity of nanostructured AgI/TiO2 photocatalyst [J].
Li, Yuanzhi ;
Zhang, Hua ;
Guo, Zhimin ;
Han, Jianjun ;
Zhao, Xiujian ;
Zhao, Qingnan ;
Kim, Sun-Jae .
LANGMUIR, 2008, 24 (15) :8351-8357
[8]   Synthesis and characterization of carbon-doped titania as an artificial solar light sensitive photocatalyst [J].
Li, YZ ;
Hwang, DS ;
Lee, NH ;
Kim, SJ .
CHEMICAL PHYSICS LETTERS, 2005, 404 (1-3) :25-29
[9]   Origin of photoactivity of nitrogen-doped titanium dioxide under visible light [J].
Livraghi, Stefano ;
Paganini, Maria Cristina ;
Giamello, Elio ;
Selloni, Annabella ;
Di Valentin, Cristiana ;
Pacchioni, Gianfranco .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (49) :15666-15671
[10]   A novel method for the synthesis of titania nanotubes using sonoelectrochemical method and its application for photoelectrochemical splitting of water [J].
Mohapatra, S. K. ;
Misra, M. ;
Mahajan, V. K. ;
Raja, K. S. .
JOURNAL OF CATALYSIS, 2007, 246 (02) :362-369