Synthesis and Luminescent Properties of M2V2O7: Eu (M=Sr, Ba) Nanophosphors

被引:23
作者
Sheetal [1 ]
Taxak, V. B. [1 ]
Khatkar, S. P. [1 ]
机构
[1] Maharshi Dayanand Univ, Dept Chem, Rohtak 124001, Haryana, India
关键词
Nanophosphor; Luminescence; Sr2V2O7: Eu; Ba2V2O7: Eu; VISIBLE UP-CONVERSION; CRYSTAL-STRUCTURE; STRONTIUM PYROVANADATE; PHOSPHORS; VANADATES;
D O I
10.1007/s10895-011-1027-8
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
A solution combustion route for the synthesis of Eu3+-activated M2V2O7 (M = Sr, Ba) and their luminescent properties have been investigated. Structure and luminescent characteristics of Sr2V2O7:Eu3+ and Ba2V2O7:Eu3+ nanophosphors have been studied by x-ray diffraction, scanning electron microscopy, transmission electron microscopy, fluorescence spectrometry and Fourier transform infra-red spectroscopy. The incorporation of Eu3+ activator in these nanoparticles has been checked by luminescence characteristics. These nanoparticles have displayed red color under a UV source which is due to characteristics transition of Eu3+ from D-5(0) -> F-7(2) at 613 nm in both Sr2V2O7:Eu3+ and Ba2V2O7:Eu3+ nanophosphors. In addition, the optimal Eu3+ - doped contents of Sr2(1-x)Eu2xV2O7 and Ba2(1-x)Eu2xV2O7 nanophosphors for both were 4 mol%.
引用
收藏
页码:891 / 897
页数:7
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