Asymmetric Paper Supercapacitor Based on Amorphous Porous Mn3O4 Negative Electrode and Ni(OH)2 Positive Electrode: A Novel and High-Performance Flexible Electrochemical Energy Storage Device

被引:202
|
作者
Feng, Jin-Xian [1 ]
Ye, Sheng-Hua [1 ]
Lu, Xue-Feng [1 ]
Tong, Ye-Xiang [1 ]
Li, Gao-Ren [1 ]
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Lab Bioinorgan & Synthet Chem, KLGHEI Environm & Energy Chem, Guangzhou 510275, Guangdong, Peoples R China
关键词
asymmetric supercapacitor; paper-based; amorphous Mn3O4; negative electrode; flexible; porous structure; CORE-SHELL NANOWIRES; CARBON NANOTUBE YARN; CONDUCTIVE PAPER; GRAPHENE; CAPACITANCE; ARRAYS; ARCHITECTURE; TEXTILES; DESIGN; SHEETS;
D O I
10.1021/acsami.5b02157
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Here we synthesize novel asymmetric all-solid-state paper supercapacitors (APSCs). based on amorphous porous Mn3O4 grown on conducting paper (NGP), (Mn3O4/NGP) negative electrode and Ni(OH)(2) grown on NGP (Ni(OH)(2)/NGP) as positive electrode, and they have attracted intensive research interest owing to their, outstanding properties such as being flexible, ultrathin; and lightweight. The fabricated APSCs exhibit a high areal C-sp of 3.05 F/cm(3) and superior cycling stability The novel asymmetric APSCs also exhibit high energy density of 0.35 mW h/cm(3), high power density of 32.5 mW/cm(3), and superior cycling performance (<17% capacitance loss after 12 000 cycles at a high scan rate of 100 mV/s). This work shows the first example of amorphous porous metal oxide/NGP electrodes for the asymmetric APSCs; and these systems hold great potential for future flexible electronic devices.
引用
收藏
页码:11444 / 11451
页数:8
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