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Asymmetric Paper Supercapacitor Based on Amorphous Porous Mn3O4 Negative Electrode and Ni(OH)2 Positive Electrode: A Novel and High-Performance Flexible Electrochemical Energy Storage Device
被引:202
|作者:
Feng, Jin-Xian
[1
]
Ye, Sheng-Hua
[1
]
Lu, Xue-Feng
[1
]
Tong, Ye-Xiang
[1
]
Li, Gao-Ren
[1
]
机构:
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Lab Bioinorgan & Synthet Chem, KLGHEI Environm & Energy Chem, Guangzhou 510275, Guangdong, Peoples R China
关键词:
asymmetric supercapacitor;
paper-based;
amorphous Mn3O4;
negative electrode;
flexible;
porous structure;
CORE-SHELL NANOWIRES;
CARBON NANOTUBE YARN;
CONDUCTIVE PAPER;
GRAPHENE;
CAPACITANCE;
ARRAYS;
ARCHITECTURE;
TEXTILES;
DESIGN;
SHEETS;
D O I:
10.1021/acsami.5b02157
中图分类号:
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
Here we synthesize novel asymmetric all-solid-state paper supercapacitors (APSCs). based on amorphous porous Mn3O4 grown on conducting paper (NGP), (Mn3O4/NGP) negative electrode and Ni(OH)(2) grown on NGP (Ni(OH)(2)/NGP) as positive electrode, and they have attracted intensive research interest owing to their, outstanding properties such as being flexible, ultrathin; and lightweight. The fabricated APSCs exhibit a high areal C-sp of 3.05 F/cm(3) and superior cycling stability The novel asymmetric APSCs also exhibit high energy density of 0.35 mW h/cm(3), high power density of 32.5 mW/cm(3), and superior cycling performance (<17% capacitance loss after 12 000 cycles at a high scan rate of 100 mV/s). This work shows the first example of amorphous porous metal oxide/NGP electrodes for the asymmetric APSCs; and these systems hold great potential for future flexible electronic devices.
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页码:11444 / 11451
页数:8
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