Fischer-Tropsch synthesis on monolithic catalysts with oil circulation

被引：46
作者：
Hilmen, AM
Bergene, E
Lindvåg, OA
Schanke, D
Eri, S
Holmen, A [1 ]
机构：
[1] Norwegian Univ Sci & Technol, Dept Chem Engn, NO-7491 Trondheim, Norway
[2] SINTEF, NO-7465 Trondheim, Norway
[3] STATOIL, R&D Ctr, NO-7005 Trondheim, Norway
来源：
CATALYSIS TODAY | 2005年 / 105卷 / 3-4期
关键词：
Fischer-Tropsch synthesis; monolithic catalysts; oil circulation;
D O I：
10.1016/j.cattod.2005.06.032
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Monolithic catalysts made of cordierite and gamma-Al2O3 have been prepared and tested for the Fischer-Tropsch (FT) synthesis. When operated without oil circulation, washcoated cordierite monoliths have previously been shown to be as active and selective as the corresponding powder catalyst provided that the monoliths have low washcoat loadings. Two-phase operation, i.e. with oil/product circulation during reaction, resulted in improved heat removal and temperature control, in lower apparent activity and faster deactivation, but the C5+ selectivity was equal to or even better than without oil circulation. The lower apparent activities obtained with oil circulation seem to be a combination of catalyst deactivation and flow-related problems in the present experimental set-up. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：357 / 361
页数：5
相关论文
共 13 条
[1]  
[Anonymous], SPECTRE COMP NATL SE
[2]   Monolith loop catalytic membrane reactor for Fischer-Tropsch synthesis [J].
Bradford, MCJ ;
Te, M ;
Pollack, A .
APPLIED CATALYSIS A-GENERAL, 2005, 283 (1-2) :39-46
[3]   Is a monolithic loop reactor a viable option for Fischer-Tropsch synthesis? [J].
de Deugd, RM ;
Chougule, RB ;
Kreutzer, MT ;
Meeuse, FM ;
Grievink, J ;
Kapteijn, F ;
Moulijn, JA .
CHEMICAL ENGINEERING SCIENCE, 2003, 58 (3-6) :583-591
[4]   Using monolithic catalysts for highly selective Fischer-Tropsch synthesis [J].
de Deugd, RM ;
Kapteijn, F ;
Moulijn, JA .
CATALYSIS TODAY, 2003, 79 (1-4) :495-501
[5]  
EDVINSSON R, 1994, THESIS CTH GOTEBORG
[6]  
Hilmen A.M., 2000, STUD SURF SCI CATAL, V130, P1163
[7]   Fischer-Tropsch synthesis on monolithic catalysts of different materials [J].
Hilmen, AM ;
Bergene, E ;
Lindvåg, OA ;
Schanke, D ;
Eri, S ;
Holmen, A .
CATALYSIS TODAY, 2001, 69 (1-4) :227-232
[8]   SELECTIVITY CONTROL AND CATALYST DESIGN IN THE FISCHER-TROPSCH SYNTHESIS - SITES, PELLETS, AND REACTORS [J].
IGLESIA, E ;
REYES, SC ;
MADON, RJ ;
SOLED, SL .
ADVANCES IN CATALYSIS, VOL 39, 1993, 39 :221-302
[9]   SYNTHESIS AND CATALYTIC PROPERTIES OF EGGSHELL COBALT CATALYSTS FOR THE FISCHER-TROPSCH SYNTHESIS [J].
IGLESIA, E ;
SOLED, SL ;
BAUMGARTNER, JE ;
REYES, SC .
JOURNAL OF CATALYSIS, 1995, 153 (01) :108-122
[10]   A multifunctional reactor with a regular catalyst packing for Fischer-Tropsch synthesis [J].
Mesheryakov, VD ;
Kirillov, VA ;
Kuzin, NA .
CHEMICAL ENGINEERING SCIENCE, 1999, 54 (10) :1565-1570
12