Photofunctional nanomaterials composed of multiporphyrins and carbon-based π-electron acceptors

被引:295
作者
Fukuzumi, Shunichi [1 ]
Kojima, Takahiko [1 ]
机构
[1] Osaka Univ, SORST, Japan Sci & Technol Agcy, Grad Sch Engn,Dept Mat & Life Sci, Suita, Osaka 5650871, Japan
关键词
D O I
10.1039/b717958h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent development of artificial photosynthetic systems using photofunctional nanomaterials composed of multiporphyrins and carbon-based pi-electron acceptors such as fullerenes, carbon nanotubes and a new type of nanocarbon is reviewed by focusing on their photoinduced electron-transfer properties. Electron donor-acceptor ensembles composed of porphyrins and fullerenes are described, covering small electron donor-acceptor dyads to larger multi-component systems including porphyrin-based photofunctional nanometerials. Such photofunctional nanomaterials composed of multiporphyrins and carbon-based pi-electron acceptors (in particular C-60) have been utilized to construct efficient light energy conversion systems such as photovoltaic devices.
引用
收藏
页码:1427 / 1439
页数:13
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