Self-Assembly and Exfoliation of a Molecular Solid Based on Cooperative B-N and Hydrogen Bonds

被引：12
作者：
Fornasari, Luca [1 ]
Mazzaro, Raffaello [2 ,3 ]
Boanini, Elisa [1 ]
d'Agostino, Simone [1 ]
Bergamini, Giacomo [1 ]
Grepioni, Fabrizia [1 ]
Braga, Dario [1 ]
机构：
[1] Univ Bologna, Dipartimento Chim Giacomo Ciamician, Via F Selmi 2, I-40126 Bologna, Italy
[2] Lulea Tekniska Univ, Dept Engn Sci & Math, S-97187 Lulea, Sweden
[3] CNR, Area Ric Bologna, IMM, Via P Gobetti 101, I-40129 Bologna, Italy
来源：
CRYSTAL GROWTH & DESIGN | 2018年 / 18卷 / 12期
关键词：
BORON-NITROGEN BONDS; BUILDING-BLOCKS; COORDINATION; POLYMERS; MACROCYCLES; CHEMISTRY; PYRIDYL; DESIGN; ESTERS; ACID;
D O I：
10.1021/acs.cgd.8b01674
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein we report that 4-pyridinylboronic acid (1) in the solid state self-assembles into tetrameric macrocycles via B-N bond formation. The tetramers are linked via O-H center dot center dot center dot O bonds resulting in a material that can be exfoliated via sonication to give thinner sheets as we demonstrate via Fourier transform infrared spectroscopy, transmission electron microscopy, selected area electron diffraction, and atomic force microscopy experiments. For comparison, the structure of the related compound 4-(pyridin-4-yl) phenylboronic acid (2) is also discussed.
引用
收藏
页码：7259 / 7263
页数：5
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